Answer:
not affected?
Explanation:
pretty sure M / concentration isn't affected, only volume.
Answer:
8.279
Explanation:
The pH can be determined by hydrolysis of a conjugate base of weak acid at the equivalence point.
At the equivalence point, we have

= 25.00 x 0.200
= 5.00 m-mol
= 0.005 mol
Volume of the base that is added to reach the equivalence point is

Number of moles of 
= 0.005 mol
Volume at the equivalence point is 25 + 5 = 30.00 mL
Therefore, concentration of 
= 0.167 M
Now the ICE table :

I (M) 0.167 0 0
C (M) -x +x +x
E (M) 0.167-x x x
Now, the value of the base dissociation constant is ,



= 
Base ionization constant, ![$K_b = \frac{\left[HNO_2\right] \left[OH^- \right]}{\left[NO^-_2 \right]}$](https://tex.z-dn.net/?f=%24K_b%20%3D%20%5Cfrac%7B%5Cleft%5BHNO_2%5Cright%5D%20%5Cleft%5BOH%5E-%20%5Cright%5D%7D%7B%5Cleft%5BNO%5E-_2%20%5Cright%5D%7D%24)


So, ![$[OH^-]=1.9054 \times 10^{-6 } \ M$](https://tex.z-dn.net/?f=%24%5BOH%5E-%5D%3D1.9054%20%5Ctimes%2010%5E%7B-6%20%7D%20%5C%20M%24)
pOH =- ![$\log[OH^-]$](https://tex.z-dn.net/?f=%24%5Clog%5BOH%5E-%5D%24)
= 
=5.72
Now, since pH + pOH = 14
pH = 14.00 - 5.72
= 8.279
Therefore the ph is 8.279 at the end of the titration.