Answer:
Explanation:
Hess's Law of Constant Heat Summation states that if a chemical equation can be written as the sum of several other chemical equations, the enthalpy change of the first chemical equation is equal to the sum of the enthalpy changes of the other chemical equations. Thus, the reaction that involves the conversion of reactant A to B, for example, has the same enthalpy change even if you convert A to C, before converting it to B. Regardless of how many steps it takes for the reactant to be converted to the product, the enthalpy change of the overall reaction is constant.
With Hess's Law in mind, let's see how A can be converted to 2C +E.
(Δ
) -----(1)
Since we have 2B, multiply the whole of II. by 2:
(2Δ
) -----(2)
This step converts all the B intermediates to 2C +2D. This means that the overall reaction at this stage is 
.
Reversing III. gives us a negative enthalpy change as such:
(-Δ
) -----(3)
This step converts all the D intermediates formed from step (2) to E. This results in the overall equation of 
, which is also the equation of interest.
Adding all three together:
(
)
Thus, the first option is the correct answer.
Supplementary:
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Answer:
ΔS = -661.0J/mol is the entropy change for the system
ΔS = -842J/mol.K is the entropy change for the surroundings
Explanation:
From the relationship between ΔG, T, ΔH and ΔS,
Mathematically, ΔG = ΔH - TΔS
TΔS = ΔH - ΔS
ΔS = ΔH - ΔS / T
but ΔG = -54 kJ/mol, ΔH = -251 kJ/mol and T = 25 °C (298 K)
plugging into the equation,
ΔS = -251 kJ/mol - ( -54 kJ/mol) / 298
ΔS = -0.6610KJ/mol or in J.mol
ΔS = -661.0J/mol is the entropy change for the system
- For entropy change for the surroundings = ΔS = ΔH/T
- ΔS = -0.84KJ/mol.K or -842J/mol.K is the entropy change for the surroundings
The first reason to repeat experiments is simply to verify results. Different science disciplines have different criteria for determining what good results are. Biological assays, for example must be done in at least triplicate to generate acceptable data. Science is built on the assumption that published experimental protocols are repeatable.
2) The next reason to repeat experiments is to develop skills necessary to extend established methods and develop new experiments. “Practice make perfect” is true for the concert hall and the chemical laboratory.
3) Refining experimental observations is another reason to repeat. Maybe you did not follow the progress of the reaction like you should have.
4) Another reason to repeat experiments is to study and/or improve them in way. In the synthetic chemistry laboratory, for example, there is always a desire to improve the yield of a synthetic step. Will certain changes in the experimental conditions lead to a better yield? The only way to find out is to try it! The scientific method informs us that it is best to only make one change at a time.
5) The final reason to repeat an extraction, chromatographic or synthetic protocol is to produce more of your target substance. This is sometimes referred to scale-up.
Answer:
The rusting of iron is spontaneous at low temperatures.
Explanation:
The given chemical reaction is:
4Fe(s) + 3O2(g) ----> 2Fe2O3(s) [rust]
The rusting of iron is a chemical reaction in which iron reacts with oxygen in presence of moisture and forms iron oxide.
This reaction takes place in a faster rate when there is low temperatures in the atmosphere.
When temperature is low, the moisture in the atmosphere is more and hence, rate of rusting is more.
Answer:
Average density of the liquid = 0.992 g/mL
Explanation:
Density = mass/volume
mass of liquid = (mass of liquid + mass of cylinder) - mass of cylinder
Trial 1: mass of liquid = 19.731 - 9.861 = 9.87
volume of liquid = 10 mL
density of liquid = 9.87 g / 10 mL = 0.987 g/mL
Trial 2: mass of liquid = 19.831 - 9.861 = 9.97
volume of liquid = 10 mL
density of liquid = 9.97 g / 10 mL = 0.997 g/mL
Trial 3: mass of liquid = 19.831 - 9.861 = 9.97
volume of liquid = 10 mL
density of liquid = 9.97 g / 10 mL = 0.997 g/mL
Trial 4: mass of liquid = 19.771 - 9.861 = 9.91
volume of liquid = 10 mL
density of liquid = 9.91 g / 10 mL = 0.991 g/mL
Trial 5: mass of liquid = 19.751 - 9.861 = 9.89
volume of liquid = 10 mL
density of liquid = 9.89 g / 10 mL = 0.989 g/mL
Average density = (0.987 + 0.997 + 0.997 + 0.991 + 0.989)/5 = 4.961/5
Average density of the liquid = 0.992 g/mL
