Answer:
The pH of 0.1 M BH⁺ClO₄⁻ solution is <u>5.44</u>
Explanation:
Given: The base dissociation constant:
= 1 × 10⁻⁴, Concentration of salt: BH⁺ClO₄⁻ = 0.1 M
Also, water dissociation constant:
= 1 × 10⁻¹⁴
<em><u>The acid dissociation constant </u></em>(
)<em><u> for the weak acid (BH⁺) can be calculated by the equation:</u></em>

<em><u>Now, the acid dissociation reaction for the weak acid (BH⁺) and the initial concentration and concentration at equilibrium is given as:</u></em>
Reaction involved: BH⁺ + H₂O ⇌ B + H₃O+
Initial: 0.1 M x x
Change: -x +x +x
Equilibrium: 0.1 - x x x
<u>The acid dissociation constant: </u>![K_{a} = \frac{\left [B \right ] \left [H_{3}O^{+}\right ]}{\left [BH^{+} \right ]} = \frac{(x)(x)}{(0.1 - x)} = \frac{x^{2}}{0.1 - x}](https://tex.z-dn.net/?f=K_%7Ba%7D%20%3D%20%5Cfrac%7B%5Cleft%20%5BB%20%5Cright%20%5D%20%5Cleft%20%5BH_%7B3%7DO%5E%7B%2B%7D%5Cright%20%5D%7D%7B%5Cleft%20%5BBH%5E%7B%2B%7D%20%5Cright%20%5D%7D%20%3D%20%5Cfrac%7B%28x%29%28x%29%7D%7B%280.1%20-%20x%29%7D%20%3D%20%5Cfrac%7Bx%5E%7B2%7D%7D%7B0.1%20-%20x%7D)





<u>Therefore, the concentration of hydrogen ion: x = 3.6 × 10⁻⁶ M</u>
Now, pH = - ㏒ [H⁺] = - ㏒ (3.6 × 10⁻⁶ M) = 5.44
<u>Therefore, the pH of 0.1 M BH⁺ClO₄⁻ solution is 5.44</u>
Answer: b} The exact time when an individual atom will decay can be accurately predicted.
c} After each half-life, the amount of radioactive material is reduced by half.
Explanation:
All radioactive decay follows first order kinetics.
Rate law expression for first order kinetics is given by:
where,
k = rate constant
t = time taken for decay process
a = initial amount of the reactant
a - x = amount left after decay process
Expression for calculating half life, which is the time taken by the half of the reactants to decompose is:

1. The molar mass of Fe2(CO3)3 is 291.72 g/mol. This means that 45.6 g is equivalent to 0.156 mol. Dividing by the 0.167 L of water gives a solution of 0.936 M.
2. Multiplying (0.672 M)(0.025 L) = 0.0168 mol. The molar mass of Ni(OH)2 is 92.71 g/mol, so multiplying by 0.0168 mol = 1.56 grams. Therefore you would need to dissolved 1.56 g of Ni(OH)2 into 25 mL of water.
3. Fe2(CO3)3 + Ni(OH)2 --> Fe(OH)3 + NiCO3Balancing: Fe2(CO3)3 + 3Ni(OH)2 --> 2Fe(OH)3 + 3NiCO3The reaction quotient is:[Fe(OH)3]^2 * [NiCO3]^3 / [Fe2(CO3)3][Ni(OH)2]^3= (0.05)^2 * (1.45)^3 / (0.936)(0.672)^3= 0.0268Since this is < 1, it implies that the reactants are favored at equilibrium.
The genotype for some with attached earlobes would be ee because unattached earlobes are dominant(EE or Ee) which means attached would be recessive(ee).