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marin [14]
3 years ago
5

Se construye una pila galvánica con una barra de cobre sumergida en una disolución 1M de cationes Fe+2 y una barra de plata sume

rgida en una disolución 1M de da cationes Ag+ , Calcular el potencial estándar de la celda teniendo en cuenta que a 25°C: Cu+2/Cu = -0.34V Ag+/Ag = 0.80V
Chemistry
1 answer:
pashok25 [27]3 years ago
4 0

Answer:

El potencial celular estándar, E_{cell} is +0.46 V

Explanation:

Las reacciones de media célula son;

Media reacción del ánodo Cu²⁺ + 2e⁻ ↔ Cu, E ° = 0.34 V

Media reacción catódica 2Ag + 2e⁻ ⁻ 2Ag, E ° = 0.80 V

Sin embargo tenemos para hierro Fe²⁺ + 2e⁻ ↔ Fe, E ° -0.44 V

y Fe³⁺ + e⁻ ↔ Fe²⁺, E ° = 0.77 V

 que es más alta que la del cobre presente, por lo tanto, el cobre se oxidará en el ánodo

Por lo tanto, en el ánodo, tendremos

Cu → Cu²⁺ + 2e⁻ (E ° = -0.34 V)

En el cátodo

2Ag + 2e⁻ → 2Ag (E ° = 0.80 V)

E_{cell} = E_c + E_a = -0.34 + 0.8 = +0.46 \, V

El potencial celular estándar, E_{cell} = +0.46 V

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