Answer:
Both reactions share a common intermediate and differ only in the leaving group
Explanation:
The elimination reaction of tertiary alkyl halides usually occur by E1 mechanism. In E1 mechanism, the substrate undergoes ionization leading to the loss of a leaving group and formation of a carbocation.
Loss of a proton from the carbocation completes the reaction mechanism yielding the desired alkene.
In the cases of t-butanol and t-butyl bromide, the mechanism is the same. The both reactions proceed by E1 mechanism. The leaving groups in each case are water and chloride ion respectively.
Answer : The specific heat of the metal is, 
Explanation :
In this problem we assumed that heat given by the hot body is equal to the heat taken by the cold body.


where,
= specific heat of metal = ?
= specific heat of water = 
= mass of metal = 97 g
= mass of water = 122 g
= final temperature of mixture = 
= initial temperature of metal = 
= initial temperature of water = 
Now put all the given values in the above formula, we get


Therefore, the specific heat of the metal is, 
The keyword here is gas condenses to a liquid, which mean we're talking about condensation process
The enthalpy energy in condensation process is negative because it releases energy
The entropy in general will also decreases .
Temperature affect this change because it will create free energy if added with this result
hope this helps
Answer:
pKa of the histidine = 9.67
Explanation:
The relation between standard Gibbs energy and equilibrium constant is shown below as:
R is Gas constant having value = 0.008314 kJ / K mol
Given temperature, T = 293 K
Given,
So, Applying in the equation as:-
Thus,
![\frac{[His]}{[His+]}=e^{\frac{15}{-0.008314\times 293}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D%3De%5E%7B%5Cfrac%7B15%7D%7B-0.008314%5Ctimes%20293%7D)
![\frac{[His]}{[His+]}=0.00211](https://tex.z-dn.net/?f=%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D%3D0.00211)
Also, considering:-
![pH=pKa+log\frac{[His]}{[His+]}](https://tex.z-dn.net/?f=pH%3DpKa%2Blog%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D)
Given that:- pH = 7.0
So, 
<u>pKa of the histidine = 9.67</u>