2 Li(s) +Cl₂→ 2 Li⁺ (aq) + 2Cl⁻ (aq)
The cell potential of the reaction above is +4.40V
<em><u>calculation</u></em>
Cell potential =∈° red - ∈° oxidation
in reaction above Li is oxidized from oxidation state 0 to +1 therefore the∈° oxid = -3.04
Cl is reduce from oxidation state 0 to -1 therefore the ∈°red = +1.36 V
cell potential is therefore = +1.36 v -- 3.04 = + 4.40 V
Explanation:
1. Thermochemical equation is balance stoichiometric chemical equation written with the phases of the reactants and products in the brackets along with the enthalpy change of the reaction.
The given correct thermochemical reactions are:
2. Phase change affect the value of the enthalpy change of the thermochemical equation. This is because change in phase is accompanied by change in energy. For example:
In both reaction phase of water is changing with change in energy of enthalpy of reaction.
Answer:
pure water will have the lowest boiling point.
<span>5.5×10−2M in calcium chloride and 8.0×10−2M in magnesium nitrate.
What mass of sodium phosphate must be added to 1.5L of this solution to completely eliminate the hard water ion
1) Content of Ca (2+) ions
Calcium chloride = CaCl2
Ionization equation: CaCl2 ---> Ca (2+) + 2 Cl (-)
=> Molar ratios: 1 mol of CaCl2 : 1 mol Ca(2+) : 2 mol Cl(-)
Calculate the number of moles of CaCl2 in 1.5 liters of 5.5 * 10^-2 M solution
M = n / V => n = M*V = 5.5 * 10^ -2 M * 1.5 l = 0.0825 mol CaCl2
=> 0.0825 mol Ca(2+)
2) Number of phosphate ions needed to react with 0.0825 mol Ca(2+)
formula of phospahte ion: PO4 (3-)
molar ratio: 2PO4(3-) + 3Ca(2+) = Ca3 (PO4)2
Proportion: 2 mol PO4(3-) / 3 mol Ca(2+) = x / 0.0825 mol Ca(2+)
=> x = 0.0825 coml Ca(2+) * 2 mol PO4(3-) / 3 mol Ca(2+) = 0.055 mol PO4(3-)
3) Content of Mg(2+) ions
Ionization equation: Mg (NO3)2 ----> Mg(2+) + 2 NO3 (-)
Molar ratios: 1 mol Mg(NO3)2 : 1 mol Mg(2+) + 2 mol NO3(-)
number of moles of Mg(NO3)2 in 1.5 liter of 8.0 * 10^-2 M solution
n = M * V = 8.0 * 10^ -2 M * 1.5 liter = 0.12 moles Mg(NO3)2
ions of Mg(2+) = 0.12 mol Mg(NO3)2 * 1 mol Mg(2+) / mol Mg(NO3)2 = 0.12 mol Mg(2+)
4) Number of phosphate ions needed to react with 0.12 mol Mg(2+)
2PO4(3-) + 3Mg(2+) = Mg3(PO4)2
=> 2 mol PO4(3-) / 3 mol Mg(2+) = x / 0.12 mol Mg(2+)
=> x = 0.12 * 2/3 mol PO4(3-) = 0.16 mol PO4(3-)
5) Total number of moles of PO4(3-)
0.055 mol + 0.16 mol = 0.215 mol
6) Sodium phosphate
Sodium phosphate = Na3(PO4)
Na3PO4 ---> 3Na(+) + PO4(3-)
=> 1 mol Na3PO4 : 1 mol PO4(3-)
=> 0.215 mol PO4(3-) : 0.215 mol Na3PO4
mass in grams = number of moles * molar mass
molar mass of Na3 PO4 = 3*23 g/mol + 31 g/mol + 4*16 g/mol = 164 g/mol
=> mass in grams = 0.215 mol * 164 g/mol = 35.26 g
Answer: 35.26 g of sodium phosphate
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