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3 years ago

What are isoelectronic and isostructural species?

1 answer:

8 0

Isoelectronic species are ions or elements that have equal number of electrons. From the root word, electron of the word isoelectronic. On the other hand, isotructural species are compounds with the same structures.Hope this answers the question.

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A sample of gas has a pressure of 47.5 mm in a 125-ml flask. the sample is transferred to a new flask, where it has a pressure o

Lilit [14]

P1v1=p2v2
47.5*125=66.2*v2
v2= p1v1/p2
=(47.5)(125)/(66.2)
=89.69ml

4 0

2 years ago

In chromatography why is it important to remove the strip of paper until it reaches the end

Zielflug [23.3K]

<h3>Answer:</h3>

$\:$

Because the water doesn't have to reach all the way to the top.

6 0

2 years ago

A 25.0 mL solution of 0.100 M CH3COOH is titrated with a 0.200 M KOH solution. Calculate the pH after the following additions of

zaharov [31]

Answer:

a) pH = 2.88

b) pH = 4.598

c) pH = 5.503

d) pH = 8.788

e) pH = 12.097

Explanation:

CH3COOH ↔ CH3COO- + H3O+

∴ Ka = 1.75 E-5 = [H3O+]*[CH3COO-] / [CH3COOH]

a) 0.0 mL KOH:

mass balance:

⇒ C CH3COOH = [CH3COOH] + [CH3COO-] = 0.100 M

charge balance:

⇒ [H3O+] = [CH3COO-]

⇒ 1.75 E-5 = [H3O+]²/(0.100 - [H3O+])

⇒ [H3O+]² + 1.75 E-5[H3O+] - 1.75 E-6 = 0

⇒ [H3O+] = 1.314 E.3 M

∴ pH = - Log [H3O+]

⇒ pH = 2.88

b) 5.0 mL KOH:

CH3COOH + KOH ↔ CH3COONa + H2O

∴ C CH3COOH = ((0.025)(0.100) - (5 E-3)(0.200))/(0.025+5 E-3)

⇒ C CH3COOH = 0.05 M

∴ C KOH = ((5 E-3)(0,200))/(0.025+5 E-3) = 0.033 M

mass balance:

⇒ C CH3COOH + C KOH = [CH3COOH] + [CH3COO-] = 0.05 + 0.033 = 0.083 M

charge balance:

⇒ [H3O+] + [K+] = [CH3COO-]

⇒ [CH3COO-] = [H3O+] + 0.033

⇒ 1.75 E-5 = ([H3O+]*([H3O+] + 0.033))/(0.083 - ([H3O+] + 0.033))

⇒ 1.75 E-3 = ([H3O+]² + 0.033[H3O+])/(0.05 - [H3O+])

⇒ 8.75 E-7 - 1.75 E-5[H3O+] = [H3O+]² + 0.033[H3O+]

⇒ [H3O+]² +0.03302[H3O+] - 8.75 E-7 = 0

⇒ [H3O+] = 2.523 E-5 M

⇒ pH = 4.598

equivalent point:

(C*V)acid = (C*V)base

⇒ (0.100 M)*(0.025 L) = (0.200 M)( Vbase)

⇒ Vbase = 0.0125L = 12.5 mL

c) 10.0 mL KOH:

∴ C CH3COOH = 0.0143 M

∴ C KOH = 0.057 M

as in the previous point, starting from the mass and charge balances, we obtain:

⇒ [H3O+] = 3.1386 E-6 M

⇒ pH = 5.503

d) 12.5 mL KOH:

at the equivalence point, there is complete salt formation, then the pH is calculated through the salt:

CH3COO- + H2O ↔ CH3COOH - OH-

∴ Kw/Ka = 1 E-14/1.75 E-5 = 5.714 E-10 = [CH3COOH]*[OH-]/[CH3COO-]

∴ [CH3COO-] = (0.025)(0.100))/(0.025+0.0125) = 0.066 M

mass balance:

⇒ 0.066 = [CH3COOH] + [CH3COO-]..........(1)

charge balance:

⇒ [K+] = [OH-] + [CH3COO-] = 0.066 M.........(2)

∴ [K+] = C CH3COO- = 0.066 M

(1) = (2):

⇒ [OH-] = [CH3COOH].......(3)

⇒ 5.714 E-10 = [OH-]² / (0.066 - [OH-])

⇒ [OH-]² + 5.714 E-10[OH-] - 3.7712 E-11 = 0

⇒ [OH-] = 6.1408 e-6 m

⇒ pOH = 5.212

⇒ pH = 14 - pOH = 8.788

d) 15.0 mL KOH:

after the equivalence point there is salt and excess base (OH-); ph is calculated from excess base:

⇒ C KOH = ((0.015)(0.200) - (0.025)(0.100)) / (0.025 + 0.015) = 0.0125 M

⇒ [OH-] ≅ C KOH = 0.0125 M

⇒ pOH = 1.903

⇒ pH = 12.097

8 0

2 years ago

What mass of Fe(OH)3 is produced when 35 mL of 0.250 M Fe(NO3)3 solution is mixed with 55 mL of a 0.180 M

Zina [86]

Answer:

0.35 g.

Explanation:

We'll begin by calculating the number of mole of Fe(NO3)3 in 35 mL of 0.250 M Fe(NO3)3 solution.

This is illustrated below:

Molarity of Fe(NO3)3 = 0.250 M

Volume = 35 mL = 35/1000 = 0.035 L

Mole of Fe(NO3)3 =?

Molarity = mole /Volume

0.250 = mole of Fe(NO3)3 / 0.035

Cross multiply

Mole of Fe(NO3)3 = 0.25 x 0.035

Mole of Fe(NO3)3 = 8.75×10¯³ mole

Next, we shall determine the number of mole of KOH in 55 mL of 0.180 M

KOH solution. This is illustrated below:

Molarity of KOH = 0.180 M

Volume = 55 mL = 55/1000 = 0.055 L

Mole of KOH =.?

Molarity = mole /Volume

0.180 = mole of KOH /0.055

Cross multiply

Mole of KOH = 0.180 x 0.055

Mole of KOH = 9.9×10¯³ mole.

Next, we shall write the balanced equation for the reaction. This is given below:

3KOH + Fe(NO3)3 —> Fe(OH)3 + 3KNO3

From the balanced equation above,

3 moles of KOH reacted with 1 mole of Fe(NO3)3 to produce 1 mole of Fe(OH)3.

Next, we shall determine the limiting reactant. This can be obtained as follow:

From the balanced equation above,

3 moles of KOH reacted with 1 mole of Fe(NO3)3.

Therefore, 9.9×10¯³ mole of KOH will react with = (9.9×10¯³ x 1)/3 = 3.3×10¯³ mole of Fe(NO3)3.

From the above illustration, we can see that only 3.3×10¯³ mole out of 8.75×10¯³ mole of Fe(NO3)3 given is needed to react completely with 9.9×10¯³ mole of KOH.

Therefore, KOH is the limiting reactant and Fe(NO3)3 is the excess reactant.

Next, we shall determine the number of mole of Fe(OH)3 produced from the reaction.

In this case, we shall use the limiting reactant because it will give the maximum yield of Fe(OH)3 as all of it is consumed in the reaction.

The limiting reactant is KOH and the mole of Fe(OH)3 produce can be obtained as follow:

From the balanced equation above,

3 moles of KOH reacted to produce 1 mole of Fe(OH)3.

Therefore, 9.9×10¯³ mole of KOH will react to produce = (9.9×10¯³ x 1)/3 = 3.3×10¯³ mole of Fe(OH)3.

Finally, we shall convert 3.3×10¯³ mole of Fe(OH)3 to grams. This can be obtained as follow:

Molar mass of Fe(OH)3 = 56 + 3(16 + 1) = 56 + 3(17) = 107 g/mol

Mole of Fe(OH)3 = 3.3×10¯³ mole

Mass of Fe(OH)3 =?

Mole = mass /Molar mass

3.3×10¯³ = Mass of Fe(OH)3 / 107

Cross multiply

Mass of Fe(OH)3 = 3.3×10¯³ x 107

Mass of Fe(OH)3 = 0.3531 ≈ 0.35 g.

Therefore, 0.35 g of Fe(OH)3 was produced from the reaction.

8 0

2 years ago

A helium balloon with a volume of 5.0 L and a pressure of 105 kPa at 25°C floats up high in the sky where the pressure is 850 mm

aalyn [17]

Answer:

volume 2- 4.011 L

8 0

2 years ago