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Harlamova29_29 [7]

4 years ago

9

Which acid is the best choice to create a buffer with ph= 3.19?

1 answer:

Crazy boy [7]4 years ago

5 0

<span>The best choice is hypochlorous acid nitrous acid (HNO2) because it has the nearest value of pK to the desired pH.
pKa of </span>nitrous acid<span> is 3.34
If we know pKa and pH values, we can calculate the required ratio of conjugate base (NO2⁻) to acid (HNO2) from the following equation:
pH=pKa + log(conc. of base)/( conc. of acid)
</span><span>3.19=3.34 + log c(NO2⁻)/c(HNO2)
</span><span>3.19 - 3.34 = log c(NO2⁻)/c(HNO2)
-0.15 = log c(NO2⁻)/c(HNO2)
c(NO2⁻)/c(HNO2) = 10⁰¹⁵ = 1.41

</span>

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