Answer:
27.60 g urea
Explanation:
The <em>freezing-point depression</em> is expressed by the formula:
In this case,
- ΔT = 5.6 - (-0.9) = 6.5 °C
m is the molality of the urea solution in X (mol urea/kg of X)
First we<u> calculate the molality</u>:
- 6.5 °C = 7.78 °C kg·mol⁻¹ * m
Now we<u> calculate the moles of ure</u>a that were dissolved:
550 g X ⇒ 550 / 1000 = 0.550 kg X
- 0.84 m = mol Urea / 0.550 kg X
Finally we <u>calculate the mass of urea</u>, using its molecular weight:
- 0.46 mol * 60.06 g/mol = 27.60 g urea
Answer:
Explanation:
Hello there!
In this case, when considering weak acids which have an associated percent dissociation, we first need to set up the ionization reaction and the equilibrium expression:
![HA\rightleftharpoons H^++A^-\\\\Ka=\frac{[H^+][A^-]}{[HA]}](https://tex.z-dn.net/?f=HA%5Crightleftharpoons%20H%5E%2B%2BA%5E-%5C%5C%5C%5CKa%3D%5Cfrac%7B%5BH%5E%2B%5D%5BA%5E-%5D%7D%7B%5BHA%5D%7D)
Now, by introducing x as the reaction extent which also represents the concentration of both H+ and A-, we have:
![Ka=\frac{x^2}{[HA]_0-x} =10^{-4.74}=1.82x10^{-5}](https://tex.z-dn.net/?f=Ka%3D%5Cfrac%7Bx%5E2%7D%7B%5BHA%5D_0-x%7D%20%3D10%5E%7B-4.74%7D%3D1.82x10%5E%7B-5%7D)
Thus, it is possible to find x given the pH as shown below:
So that we can calculate the initial concentration of the acid:
![\frac{(1.82x10^{-5})^2}{[HA]_0-1.82x10^{-5}} =1.82x10^{-5}\\\\\frac{1.82x10^{-5}}{[HA]_0-1.82x10^{-5}} =1\\\\](https://tex.z-dn.net/?f=%5Cfrac%7B%281.82x10%5E%7B-5%7D%29%5E2%7D%7B%5BHA%5D_0-1.82x10%5E%7B-5%7D%7D%20%3D1.82x10%5E%7B-5%7D%5C%5C%5C%5C%5Cfrac%7B1.82x10%5E%7B-5%7D%7D%7B%5BHA%5D_0-1.82x10%5E%7B-5%7D%7D%20%3D1%5C%5C%5C%5C)
![[HA]_0=3.64x10^{-5}M](https://tex.z-dn.net/?f=%5BHA%5D_0%3D3.64x10%5E%7B-5%7DM)
Therefore, the percent dissociation turns out to be:
![\% diss=\frac{x}{[HA]_0}*100\% \\\\\% diss=\frac{1.82x10^{-5}M}{3.64x10^{-5}M}*100\% \\\\\% diss = 50\%](https://tex.z-dn.net/?f=%5C%25%20diss%3D%5Cfrac%7Bx%7D%7B%5BHA%5D_0%7D%2A100%5C%25%20%5C%5C%5C%5C%5C%25%20diss%3D%5Cfrac%7B1.82x10%5E%7B-5%7DM%7D%7B3.64x10%5E%7B-5%7DM%7D%2A100%5C%25%20%5C%5C%5C%5C%5C%25%20diss%20%3D%2050%5C%25)
Best regards!
A compound<span> is a </span>pure substance<span> composed of two or more different atoms chemically bonded to one another. A </span>compound<span> can be destroyed by chemical means. It might be broken down into simpler </span>compounds<span>, into its elements or a combination of the two.</span>
DeltaH formation = deltaH of broken bonds - deltaH of formed bonds
Broken bonds: tiple bond N-N and H-H bond
Formed bonds: N-H and N-N bonds
You also have to take note of the molar coefficients
deltaH formation = <span> [(N≡N) + 2 * (H-H)] - [4 * (N-H) + (N-N)]
= (945 + 2*436) - (4*390 + 240)
= 17 kJ/mol
The answer is 17 kJ/mol.</span>
