The average mass of an atom is calculated with the formula:
average mass = abundance of isotope (1) × mass of isotope (1) + abundance of isotope (2) × mass of isotope (2) + ... an so on
For the boron we have two isotopes, so the formula will become:
average mass of boron = abundance of isotope (1) × mass of isotope (1) + abundance of isotope (2) × mass of isotope (2)
We plug in the values:
10.81 = 0.1980 × 10.012938 + 0.8020 × mass of isotope (2)
10.81 = 1.98 + 0.8020 × mass of isotope (2)
10.81 - 1.98 = 0.8020 × mass of isotope (2)
8.83 = 0.8020 × mass of isotope (2)
mass of isotope (2) = 8.83 / 0.8020
mass of isotope (2) = 11.009975
mass of isotope (1) = 10.012938 (given by the question)
Resonance, leaving group, carbonyl carbon delta+, and steric effect is the most crucial variables that affect the relative reactivity of a functional group containing a carbonyl in an addition or substitution process.
Discussion:
1. Carbonyl Carbon Delta+: The carbonyl group becomes more electrophilic and accelerates nucleophilic assault when the carbonyl carbon delta+ is bigger.
2. Resonance: When the carbonyl is transformed into the tetrahedral adduct, it may be lost. Loss of resonance increases the energy of the transition state for this nucleophilic assault because resonance has the function of stabilizing. Therefore, a carbonyl functional group's resistance to nucleophilic attack increases as resonance in the group increases in importance.
3. Leaving group: Tetrahedral adduct fragmentation is encouraged by a better LG.
4. Steric effects: The nucleophilic attack on carbonyl carbon is delayed when sterically impeded.
Learn more about carbonyl here:
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Saturated fat, milk, cheese, and meat.
In the first shell there is 2 electrons and on the second shell there is 4 elections.
