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In order to deprotonate an acid, we must remove protons in order to achieve a more stable conjugate base. For this example, we can use the relationship between carboxylic acid and hydroxide.
Deprotonation is the removal of a proton from a specific type of acid in reaction to its coming into contact with a strong base. The compound formed from this reaction is known as the conjugate base of that acid. The opposite process is also possible and is when a proton is added to a special kind of base. This is a process referred to as protonation, which forms the conjugate acid of that base.
For the example we have chosen to give, the conjugate base is the carboxylate salt. This would be the compound formed by the deprotonated carboxylic acid. The base in question was strong enough to deprotonate the acid due to the greater stability offered as a conjugated base.
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Answer:
See explanation.
Explanation:
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In this case, we can show how the empirical formula is found by following the shown below procedure:
1. Compute the moles of carbon in carbon dioxide as the only source of carbon at the products:
2. Compute the moles of hydrogen in water as the only source of hydrogen at the products:
3. Compute the mass of oxygen by subtracting the mass of both carbon and hydrogen from the 0.4647-g sample:
4. Compute the moles of oxygen by using its molar mass:
5. Divide the moles of carbon, hydrogen and oxygen by the moles of oxygen (smallest one) to find the subscripts in the empirical formula:
6. Search for the closest whole number (in this case multiply by 2):
Moreover, the empirical formula suggests this compound could be carboxylic acid since it has two oxygen atoms, nevertheless, this is not true since the molar mass is 222.27 g/mol, therefore, we should compute the molar mass of the empirical formula, that is:
Which is about three times in the molecular formula, for that reason, the actual formula is:
It suggest that the compound has a highly oxidizing character due to the presence of oxygen, therefore, we cannot predict the distribution of the functional groups as it could contain, carboxyl, carbonyl, hydroxyl or even peroxi.
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