Answer:

is the no. of electrons
Explanation:
Given:
- quantity of charge transferred,

<u>No. of electrons in the given amount of charge:</u>
As we have charge on one electron 
so,


is the no. of electrons
- Now if each water molecules donates one electron:
Then we require
molecules.
<u>Now the no. of moles in this many molecules:</u>

where
Avogadro No.


- We have molecular mass of water as M=18 g/mol.
<u>So, the mass of water in the obtained moles:</u>

where:
m = mass in gram


I am thinking that maybe the problem is not with the calibration. It might be that the buffered solution is already expired since at this point the solution is already not stable and will give a different pH reading than what is expected.
The kinetic energy decreases