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Mama L [17]
3 years ago
11

A solution is prepared by mixing 50.0 mL of 0.50 M Cu(NO3)2 with 50.0 mL of 0.50 M Co(NO3)2. Sodium hydroxide is added to the mi

xture. Which hydroxide precipitates first and what concentration of hydroxide ions present in solution will accomplish the separation?
Chemistry
1 answer:
vekshin13 years ago
3 0

Answer:

Cu(OH)₂ will precipitate first, with [OH⁻] = 2.97x10⁻¹⁰ M

Explanation:

The equilibriums that take place are:

Cu⁺² + 2OH⁻ ↔ Cu(OH)₂(s)   ksp = 2.2x10⁻²⁰ = [Cu⁺²]*[OH⁻]²

Co⁺² + 2OH⁻ ↔ Co(OH)₂(s)   ksp = 1.3x10⁻¹⁵ = [Co⁺²]*[OH⁻]²

Keep in mind that <em>the concentration of each ion is halved </em>because of the dilution when mixing the solutions.

For Cu⁺²:

2.2x10⁻²⁰ = [Cu⁺²]*[OH⁻]²

2.2x10⁻²⁰ = 0.25 M*[OH⁻]²

[OH⁻] = 2.97x10⁻¹⁰ M

For Co⁺²:

1.3x10⁻¹⁵ = [Co⁺²]*[OH⁻]²

1.3x10⁻¹⁵ = 0.25 M*[OH⁻]²

[OH⁻] = 7.21x10⁻⁸ M

<u>Because Copper requires less concentration of OH⁻ than Cobalt</u>, Cu(OH)₂ will precipitate first, with [OH⁻] = 2.97x10⁻¹⁰ M

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