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nignag [31]
3 years ago
11

When a diprotic acid is titrated with a strong base, and the Ka1 and Ka2 are significantly different, then the pH vs. volume plo

t of the titration will have Group of answer choices

Chemistry
1 answer:
dezoksy [38]3 years ago
4 0

Complete question is;

When a diprotic acid is titrated with a strong base, and the Ka1 and Ka2 are significantly different, then the pH vs. volume plot of the titration will have

a. a pH of 7 at the equivalence point.

b. two equivalence points below 7.

c. no equivalence point.

d. one equivalence point.

e. two distinct equivalence points

Answer:

Option E - Two Distinct Equivalence points

Explanation:

I've attached a sample diprotic acid titration curve.

In diprotic acids, the titration curves assists us to calculate the Ka1 and Ka2 of the acid. Thus, the pH at the half - first equivalence point in the titration will be equal to the pKa1 of the acid while the pH at the half - second equivalence point in a titration is equal to the pKa2 of the acid.

Thus, it is clear that there are two distinct equivalence points.

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Find the initial concentration of the weak acid or base in each of the following aqueous solutions: (a) a solution of HClO with
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To do this, you need to calculate the concentration of ions in solution with the given value of pH for each solution, then, write the chemical equation for both solutions, Set an ICE chart, use the value of Ka and Kb reported for both solutions, and solve for the initial concentration.

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This value indicates the equilibrium concentration of this ion in solution. Now, to know the initial concentration of the acid, we need to do an ICE chart and write the chemical equation. This is an acid - base reaction, so we need the value of Ka of the acid.

         HClO + H₂O <---------> H₃O⁺ + ClO⁻       Ka = 3x10⁻⁸

I:            Y                                 0          0

C:          -x                                +x         +x

E:           Y - x                            x          x

With this chart, we need to write the expression for Ka which is:

Ka = [H₃O⁺] * [ClO⁻] / [HClO] = x² / Y-x

But we already know the concentration of [H₃O⁺], which is the same for [ClO⁻], and the value of Ka, so all we have to do is replace the values in the above expression and solve for Y:

3x10⁻⁸ = (2.51x10⁻⁵)² / Y - 2.51x10⁻⁵

We can round to Y because "x" is a very small value as it's value of Ka so:

3x10⁻⁸ = (2.51x10⁻⁵)²/Y

Y = (2.51x10⁻⁵)²/3x10⁻⁸

<h2><em>Y = [HClO] = 0.021 M</em></h2>

<em>And this is the initial concentration of the acid.</em>

<u><em>b) Solution of hidrazine pH = 10.2</em></u>

We do the same procedure as part a) with the difference that instead of using Ka , we use Kb and concentration of [OH⁻]. The Kb for hydrazine is 1.3x10⁻⁶

Let's calculate the [OH⁻]:

pOH = 14 - pH

pOH = 14 - 10.2 = 3.8

[OH⁻] = 10^(-3.8) = 1.58x10⁻⁴ M

The chemical equation:

          N₂H₄ + H₂O <---------> N₂H₅⁺ + OH⁻    Kb = 1.3x10⁻⁶

I:            Y                                  0           0

C:          -x                                +x           +x

E:         Y-x                                 x           x

Kb = x²/(Y-x)

1.3x10⁻⁶ = (1.58x10⁻⁴)²/Y

Y = (1.58x10⁻⁴)²/1.3x10⁻⁶

<h2><em><u>Y = [OH⁻] = 0.019 M</u></em></h2>

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