1kg is about 2.2 pounds. So 4kg = 8.8 pounds. If that represent 19% of the total, here is the answer.
0.19*x=8.8
x=8.8/0.19
x=46.31 pounds
Answer: The initial temperature of the iron was 
Explanation:

As we know that,

.................(1)
where,
q = heat absorbed or released
= mass of iron = 360 g
= mass of water = 750 g
= final temperature = 
= temperature of iron = ?
= temperature of water = 
= specific heat of iron = 
= specific heat of water= 
Now put all the given values in equation (1), we get
![-360\times 0.450\times (46.7-x)=[750\times 4.184\times (46.7-22.5)]](https://tex.z-dn.net/?f=-360%5Ctimes%200.450%5Ctimes%20%2846.7-x%29%3D%5B750%5Ctimes%204.184%5Ctimes%20%2846.7-22.5%29%5D)

Therefore, the initial temperature of the iron was 
Solution :
"Aldol" stands for the abbreviation, aldehyde and alcohol. When a ketone or an aldehyde's enolate reacts with the carbonyl of a molecule at the alpha carbon, under the acidic or basic conditions so as to obtained the ketone or β-hydroxy aldehyde, is known as an aldol reaction.
For the conversion of the aldol addition product of a 3-hydroxy-3-(4-nitrophenyl)-1-(2-pyridyl)-1-propanone to an aldol condensation product of (E)-3-(4-nitrophenyl)-1-(2-pyridyl)-1-propenone, the mechanism is given in the diagram a below :