<u>Answer:</u> The concentration of 
required will be 0.285 M.
<u>Explanation:</u>
To calculate the molarity of 
, we use the equation:
Moles of = 0.016 moles
Volume of solution = 1 L
Putting values in above equation, we get:
For the given chemical equations:
![Ni^{2+}(aq.)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K_f=1.2\times 10^9](https://tex.z-dn.net/?f=Ni%5E%7B2%2B%7D%28aq.%29%2B6NH_3%28aq.%29%5Crightleftharpoons%20%5BNi%28NH_3%29_6%5D%5E%7B2%2B%7D%2BC_2O_4%5E%7B2-%7D%28aq.%29%3BK_f%3D1.2%5Ctimes%2010%5E9)
Net equation: ![NiC_2O_4(s)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K=?](https://tex.z-dn.net/?f=NiC_2O_4%28s%29%2B6NH_3%28aq.%29%5Crightleftharpoons%20%5BNi%28NH_3%29_6%5D%5E%7B2%2B%7D%2BC_2O_4%5E%7B2-%7D%28aq.%29%3BK%3D%3F)
To calculate the equilibrium constant, K for above equation, we get:
The expression for equilibrium constant of above equation is:
![K=\frac{[C_2O_4^{2-}][[Ni(NH_3)_6]^{2+}]}{[NiC_2O_4][NH_3]^6}](https://tex.z-dn.net/?f=K%3D%5Cfrac%7B%5BC_2O_4%5E%7B2-%7D%5D%5B%5BNi%28NH_3%29_6%5D%5E%7B2%2B%7D%5D%7D%7B%5BNiC_2O_4%5D%5BNH_3%5D%5E6%7D)
As, is a solid, so its activity is taken as 1 and so for 
We are given:
![[[Ni(NH_3)_6]^{2+}]=0.016M](https://tex.z-dn.net/?f=%5B%5BNi%28NH_3%29_6%5D%5E%7B2%2B%7D%5D%3D0.016M)
Putting values in above equations, we get:
![0.48=\frac{0.016}{[NH_3]^6}}](https://tex.z-dn.net/?f=0.48%3D%5Cfrac%7B0.016%7D%7B%5BNH_3%5D%5E6%7D%7D)
![[NH_3]=0.285M](https://tex.z-dn.net/?f=%5BNH_3%5D%3D0.285M)
Hence, the concentration of required will be 0.285 M.
Based on Le Chatelier's principle, if the equilibrium of a system is disturbed by changing the temperature, pressure or concentration, then it will shift in a direction to undo the effect of the induced change.
The given equilibrium is:
A + B ↔ AB
Removal of the reactant A implies that the concentration of A has decreased, therefore the equilibrium will shift in a direction to produce more of A. Thus, it will shift to the left and the rate of the reverse or backward reaction will increase.
Your answer is D. You're Welcome
OMG WRONG THING SOOO SOO SORRYY i mean to put this answer on something else
