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Trava [24]
3 years ago
11

Which ONE of the following compounds is least soluble in water?

Chemistry
1 answer:
Zepler [3.9K]3 years ago
4 0

Answer:

B) CH3CH2CH2F

Explanation:

All the other compounds listed among the options are capable of forming hydrogen bonds with water except CH3CH2CH2F.

Recall that hydrogen bonds are formed when hydrogen is directly bonded to a highly electronegative atom such as nitrogen, oxygen, fluorine, sulphur, et cetra.

Such bonds are not present in CH3CH2CH2F, rather fluorine is bonded to carbon to give a halogenoalkane. This compound will display the least solubility in water.

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Answer:

pH = 2.69

Explanation:

The complete question is:<em> An analytical chemist is titrating 182.2 mL of a 1.200 M solution of nitrous acid (HNO2) with a solution of 0.8400 M KOH. The pKa of nitrous acid is 3.35. Calculate the pH of the acid solution after the chemist has added 46.44 mL of the KOH solution to it.</em>

<em />

The reaction of HNO₂ with KOH is:

HNO₂ + KOH → NO₂⁻ + H₂O + K⁺

Moles of HNO₂ and KOH that react are:

HNO₂ = 0.1822L × (1.200mol / L) = <em>0.21864 moles HNO₂</em>

KOH = 0.04644L × (0.8400mol / L) = <em>0.0390 moles KOH</em>

That means after the reaction, moles of HNO₂ and NO₂⁻ after the reaction are:

NO₂⁻ = 0.03900 moles KOH = moles NO₂⁻

HNO₂ = 0.21864 moles HNO₂ - 0.03900 moles = 0.17964 moles HNO₂

It is possible to find the pH of this buffer (<em>Mixture of a weak acid, HNO₂ with the conjugate base, NO₂⁻), </em>using H-H equation for this system:

pH = pKa + log₁₀ [NO₂⁻] / [HNO₂]

pH = 3.35 + log₁₀ [0.03900mol] / [0.17964mol]

<h3>pH = 2.69</h3>
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