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3 years ago

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Chemistry

2 answers:

lutik1710 [3]3 years ago

6 0

Correct answer is <span>X = ΔH

Reason:
1) The graph of enthalpy Vs reaction coordinate suggest the reaction is endothermic in nature. For endothermic reaction, energy if product is more than that of reactant. Hence, option 1 i.e. </span><span>X = -ΔH cannot be correct.
2) Since the reaction is endothermic in nature, </span>energy if product is more than that of reactant. Hence, option 2 i.e. X = ΔH is correct.
3) Activation energy is energy difference between Reactant (A) and transition state (B). However, as per option C, activation energy (A.E.) is energy difference between product (C) and transition state (B), which is incorrect.

Gnoma [55]3 years ago

6 0

Answer:

Correct answer is X = ΔH

Explanation:

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Read 2 more answers

The reaction 2NO(g)+O2(g)−→−2NO2(g) is second order in NO and first order in O2. When [NO]=0.040M, and [O2]=0.035M, the observed

Oksanka [162]

Answer:

(a) The rate of disappearance of $O_{2}$ is: $4.65*10^{-5}$ M/s

(b) The value of rate constant is: 0.83036 $M^{-2}s^{-1}$

(d) The rate will increase by a factor of 3.24

Explanation:

The rate of a reaction can be expressed in terms of the concentrations of the reactants and products in accordance with the balanced equation.

For the given reaction:

$2NO(g)+O_{2}->2NO_{2}$

rate = $-\frac{1}{2} \frac{d}{dt}[NO]$ = $-\frac{d}{dt}[O_{2}]$ = $\frac{1}{2}\frac{d}{dt}[NO_{2}]$ -----(1)

According to the question, the reaction is second order in NO and first order in $O_{2}$ .

Then we can say that, rate = k $[NO]^{2}[O_{2}]$ -----(2)

where k is the rate constant.

The rate of disappearance of NO is given:

$-\frac{d}{dt}[NO]$ = $9.3*10^{-5}$ M/s.

(a) From (1), we can get the rate of disappearance of $O_{2}$ .

Rate of disappearance of $O_{2}$ = $-\frac{d}{dt}[O_{2}]$ = (0.5)*( $9.3*10^{-5}$ ) M/s = $4.65*10^{-5}$ M/s.

(b) The rate of the reaction can be obtained from (1).

rate = $-\frac{1}{2} \frac{d}{dt}[NO]$ = (0.5)*( $9.3*10^{-5}$ )

rate = $4.65*10^{-5}$ M/s

The value of rate constant can be obtained by using (2).

rate constant = k = $\frac{rate}{[NO]^{2}[O_{2}]}$

k = $\frac{4.65*10^{-5}}{(0.040)^{2}(0.035)}$ = 0.83036 $M^{-2}s^{-1}$

k = $\frac{rate}{[NO]^{2}[O_{2}]}$

Substituting the units of rate as M/s and concentrations as M, we get:

$\frac{Ms^{-1} }{M^{3}}$ = $M^{-2}s^{-1}$

(d) The reaction is second order in NO. Rate is proportional to square of the concentration of NO.

$rate\alpha [NO]^{2}$

If the concentration of NO increases by a factor of 1.8, the rate will increase by a factor of $(1.8)^{2}$ = 3.24

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3 years ago

The following equilibrium is formed when copper and bromide ions are placed in a solution:

JulsSmile [24]

Answer:

1. Reaction will shift rightwards towards the products.

2. It will turn green.

3. The solution will be cooler..

B) It will turn green.

Explanation:

Hello,

In this case, for the stated equilibrium:

$heat + Cu(H_2O)_6 ^{+2} (blue) + 4Br^- \rightleftharpoons 6H_2O + CuBr_4^{-2} (green)$

In such a way, by thinking out the Le Chatelier's principle, we can answer to each question:

1. If potassium bromide, which adds bromide ions, is added more reactant is being added to the solution, therefore, the reaction will shift rightwards towards the products.

2. The formation of the green complex is favored, therefore, it will turn green.

3. The solution will be cooler as heat is converted into "cold" in order to reestablish equilibrium.

B) In this case, as the heat is a reactant, if more heat is added, more products will be formed, which implies that it will turn green.

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