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Tanya [424]
3 years ago
15

Which of the following is necessary to increase the rate of a reaction?

Chemistry
1 answer:
irga5000 [103]3 years ago
6 0
Rate of Reaction ca be increased by applying following changes,

1) Increase in Temperature:
                                            Increase in Temperature results in the increase of Kinetic Energy, Hence, velocity of reactants increases and rate of collisions increases. Thus, more reactants colloid with enough energy to change into products in given time.

2) Decrease in Activation Energy:
                                                     Activation energy is the minimum amount of energy required by reactants to cross the energy barrier to convert into products. Hence, activation energy is decreased by using catalyst.

3) Concentration of Reactants:
                                                 The greater the concentration of reactants, greater is the number of reactants per volume. More reactants in less area increase the probability of collision. Hence, collisions increase and rate of reaction increases.

4) Increasing Surface Area of Reactant:
                                                               Greater the surface area greater is the rate of reaction.
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Part A:

Total pressure of the mixture = P = 5.40 atm

Volume of the container = V = 10.0 L

Temperature of the mixture = T = 23°C = 296.15 K

Total number of moles of gases = n

PV = nRT (ideal gas equation)

n=\frac{PV}{RT}=\frac{5.40 atm\times 10.0 L}{0.0821 atm L/mol K\times 296.15 K}=2.22 mol

Moles of methane gas = n_1=\frac{8.00 g}{16 g/mol}=0.5 mol

Moles of ethane gas  =n_2=\frac{18.0 g}{30 g/mol}=0.6 mol

Moles of propane gas = n_3

n=n_1+n_2+n_3

2.22=0.5 mol +0.6 mol+ n_3

n_3= 2.22 mol - 0.5 mol -0.6 mol= 1.12 mol

Mole fraction of methane =\chi_1=\frac{n_1}{n_1+n_2+n_3}=\frac{n_1}{n}

\chi_1=\frac{0.5 mol}{2.22 mol}=0.2252

Similarly, mole fraction of ethane and propane :

\chi_2=\frac{n_2}{n}=\frac{0.6 mol}{2.22 mol}=0.2703

\chi_3=\frac{n_3}{n}=\frac{1.12 mol}{2.22 mol}=0.5045

Partial pressure of each gas can be calculated by the help of Dalton's' law:

p_i=P\times \chi_1

Partial pressure of methane gas:

p_1=P\times \chi_1=5.40 atm\times 0.2252=1.22 atm

Partial pressure of ethane gas:

p_2=P\times \chi_2=5.40 atm\times 0.2703=1.46 atm

Partial pressure of propane gas:

p_3=P\times \chi_3=5.40 atm\times 0.5045=2.72 atm

Part B:

Suppose in 100 grams mixture of nitrogen and oxygen gas.

Percentage of nitrogen = 37.8 %

Mass of nitrogen in 100 g mixture = 37.8 g

Mass of oxygen gas = 100 g - 37.8 g = 62.2 g

Moles of nitrogen gas = n_1=\frac{37.8 g g}{28g/mol}=1.35 mol

Moles of oxygen gas  =n_2=\frac{62.2 g}{32 g/mol}=1.94 mol

Mole fraction of nitrogen=\chi_1=\frac{n_1}{n_1+n_2}

\chi_1=\frac{1.35 mol}{1.35 mol+1.94 mol}=0.4103

Similarly, mole fraction of oxygen

\chi_2=\frac{n_2}{n_1+n_2}=\frac{1.94 mol}{1.35 mol+1.94 mol}=0.5897

Partial pressure of each gas can be calculated by the help of Dalton's' law:

p_i=P\times \chi_1

The total pressure is 405 mmHg.

P = 405 mmHg

Partial pressure of nitrogen gas:

p_1=P\times \chi_1=405 mmHg\times 0.4103 =166.17 mmHg

Partial pressure of oxygen gas:

p_2=P\times \chi_2=405 mmHg\times 0.5897=238.83 mmHg

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