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ivann1987 [24]
4 years ago
13

Which statement about spontaneous and nonspontaneous processes is correct? Spontaneous processes are favored by a decrease in H,

but nonspontaneous reactions are favored by an increase in H. Spontaneous processes are favored by a decrease in S, but nonspontaneous reactions are favored by an increase in S. An increase in S favors both spontaneous and nonspontaneous processes. A decrease in H favors both spontaneous and nonspontaneous processes.
Chemistry
2 answers:
Marina86 [1]4 years ago
7 0
I believe your answer would be the first one

hope this helps
Sav [38]4 years ago
5 0

Answer: Spontaneous processes are favored by a decrease in H, but nonspontaneous reactions are favored by an increase in H.

Explanation:

\Delta G=\Delta H-T\Delta S

\Delta G = gibbs free energy

\Delta H = change in enthalpy

\Delta S = change in entropy

For a reaction to be spontaneous, \Delta G= -ve. For this \Delta H  has to be negative i.e. there should be a decrease in enthalpy and \Delta S has to be positive i.e. there should be a increase in entropy.

\Delta G=(-ve)-T(+ve)=-ve-ve=-ve


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II. Ionic Equations
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Complete ionic: \begin{aligned}& \rm 2\, Ag^{+}\, (aq) + 2\, {NO_3}^{-} \, (aq) + Ca^{2+}\, (aq) + 2\, Cl^{-}\, (aq) \\ & \rm \to 2\, AgCl\, (s) + Ca^{2+}\, (aq) + 2\, {NO_3}^{-}\, (aq)\end{aligned}.

Net ionic: \begin{aligned}& \rm Ag^{+}\, (aq) + Cl^{-}\, (aq) \to AgCl\, (s)\end{aligned}.

Explanation:

Start by identifying species that exist as ions. In general, such species include:

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All four species in this particular question are salts. However, only three of them are generally soluble in water: \rm AgNO_3, \rm CaCl_2, and \rm Ca(NO_3)_2. These three salts will exist as ions:

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  • Each \rm Ca(NO_3)_2 formula unit will exist as one \rm Ca^{2+} and two \rm {NO_3}^{-} ions.

On the other hand, \rm AgCl is generally insoluble in water. This salt will not form ions.

Rewrite the original chemical equation to get the corresponding ionic equation. In this question, rewrite \rm AgNO_3, \rm CaCl_2, and \rm Ca(NO_3)_2 (three soluble salts) as the corresponding ions.

Pay attention to the coefficient of each species. For example, indeed each \rm AgNO_3\, (aq) formula unit will exist as only one \rm Ag^{+} ion and one \rm {NO_3}^{-} ion. However, because the coefficient of \rm AgNO_3\, (aq)\! in the original equation is two, \!\rm AgNO_3\, (aq) alone should correspond to two \rm Ag^{+}\! ions and two \rm {NO_3}^{-}\! ions.

Do not rewrite the salt \rm AgCl because it is insoluble.

\begin{aligned}& \rm 2\, Ag^{+}\, (aq) + 2\, {NO_3}^{-} \, (aq) + Ca^{2+}\, (aq) + 2\, Cl^{-}\, (aq) \\ & \rm \to 2\, AgCl\, (s) + Ca^{2+}\, (aq) + 2\, {NO_3}^{-}\, (aq)\end{aligned}.

Eliminate ions that are present on both sides of this ionic equation. In this question, such ions include one unit of \rm Ca^{2+} and two units of \rm {NO_3}^{-}. Doing so will give:

\begin{aligned}& \rm 2\, Ag^{+}\, (aq) + 2\, Cl^{-}\, (aq) \to 2\, AgCl\, (s)\end{aligned}.

Simplify the coefficients:

\begin{aligned}& \rm Ag^{+}\, (aq) + Cl^{-}\, (aq) \to AgCl\, (s)\end{aligned}.

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