Answer:
A. there is an isotope of lanthanum with an atomic mass of 138.9
Explanation:
By knowing the different atomic masses of both Lanthanum atoms, we can not tell anything about their occurence in nature. Therefore, all the last three options are incorrect. Because, the atomic mass does not tell anything about the availability or natural abundance of an element.
Now, the isotopes of an element are those elements, which have same number of electrons and protons as the original element, but different number of neutrons. Therefore, they have same atomic number but, different atomic weight or atomic masses.
Hence, by looking at an elements having same atomic number, but different atomic masses, we can identify them as isotopes.
Thus, the correct option is:
<u>A. there is an isotope of lanthanum with an atomic mass of 138.9.</u>
A crystal is any solid that has an organized structure. ... So it is a prerequisite to be a crystal in order to be a mineral. All minerals, therefore, form crystals. On the other hand, there are crystals that are not minerals, because they are not naturally occuring, or because they are not inorganic
Source: http://www.geologyin.com/2016/03/what-is-difference-between-minerals-and.html?m=1
Answer: - 436.5 kJ.
Explanation:
According to Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.
According to this law, the chemical equation can be treated as ordinary algebraic expression and can be added or subtracted to yield the required equation.
The given chemical reaction is,
Now we have to determine the value of 
for the following reaction i.e,
According to the Hess’s law, if we divide the reaction by half then the will also get halved and on reversing the reaction , the sign of enthlapy changes.
So, the value 
for the reaction will be:
Hence, the value of for the reaction is -436.5 kJ.
Using PV=nRT or the ideal gas equation, we substitute n= 15.0 moles of gas, V= 3.00L, R equal to 0.0821 L atm/ mol K and T= 296.55 K and get P equal to 121.73 atm. The Van der waals equation is (P + n^2a/V^2)*(V-nb) = nRT. Substituting a=2.300L2⋅atm/mol2 and b=0.0430 L/mol, P is equal to 97.57 atm. The difference is <span>121.73 atm- 97.57 atm equal to 24.16 atm.</span>
