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Natalka [10]
2 years ago
7

The second-order rate constants for the reaction of oxygen atoms ·with aromatic hydrocarbons have been measured (R. Atkinson and

J.N . Pitts, J. Phys. Chem. 79, 295 (1975)). In the reaction with benzene the rate constants are 1.44x 107dm' mor ' s ' at 300.3 K, 3.03 x 107 dm' mol"'s"' at 34 1.2K, and 6.9 x 107 dm' mor's ' at 392.2K. Find the frequency factor and activation energy of the reaction.
Physics
1 answer:
Blizzard [7]2 years ago
3 0

Answer:  Frequency factor  A = 8 × 10⁹

activation energy Ea = 15.5 KJ/Mol

Explanation: to begin, let us first define the parameters given;

K₁ = 1.44 × 10⁷dm³mol⁻¹s⁻¹

K₂ = 3.03 × 10⁷ dm³mol⁻¹s⁻¹

K₃ = 6.9 × 10 dm³mol⁻¹s⁻¹

also T₁ = 300.3 K

T₂ = 341.2 K

T₃ = 392.2 K

we know that;

㏑ K₂ / K₁ = Ea/R [1/T₁ -1/T₂]

where R is given as 8.314 J/mol-k

Ea = activation energy

K₁, K₂ = rate constant

T₁, T₂ = Temperature

therefore, ㏑ (3.03 × 10⁷/ 1.44 × 10⁷) = Ea / 8.314 [1/300.3 - 1/341.2]

this gives Ea = 15496.16 J/Mol ≈ 15.5 KJ /Mol

∴ Ea = 15.5 KJ/ Mol

also given that K = A e⁻∧Ea/RT

here A = frequency factor

∴ 6.9 × 10⁷ = A e⁻ ∧(15496.16/8.314 × 392.2)

A = 7.99 × 10⁹ = 8 × 10⁹

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umka2103 [35]
<h3>Answer:  130 newtons</h3>

===============================================================

Explanation:

We'll need the acceleration first.

  • The initial speed (let's call that Vi) is 8.0 m/s
  • The final speed (Vf) is 0 m/s since Sam comes to a complete stop at the end.
  • This happens over a duration of t = 4.0 seconds

The acceleration is equal to the change in speed over change in time

a = acceleration

a = (change in speed)/(change in time)

a = (Vf - Vi)/(4 seconds)

a = (0 - 8.0)/4

a = -8/4

a = -2

The acceleration is -2 m/s^2, meaning that Sam slows down by 2 m/s every second. Negative accelerations are often associated with slowing down. The term "deceleration" can be used here.

Here's a further break down of Sam's speeds at the four points of interest

  • At 0 seconds, he's going 8 m/s
  • At the 1 second mark, he's slowing down to 8-2 = 6 m/s
  • At the 2 second mark, he's now at 6-2 = 4 m/s
  • At the 3 second mark, he's at 4-2 = 2 m/s
  • Finally, at the 4 second mark, he's at 2-2 = 0 m/s

Next, we'll apply Newton's Second Law of motion

F = m*a

where,

  • F = force applied
  • m = mass
  • a = acceleration

We just found the acceleration, and the mass is fairly easy as all we need to do is add Sam's mass with the sled's mass to get 60+5.0 = 65 kg

So the force applied must be:

F = m*a

F = 65*(-2)

F = -130 newtons

This force is negative to indicate it's pushing against the sled's momentum to slow Sam down.

The magnitude of this force is |F| = |-130| = 130 newtons

8 0
3 years ago
A dog has a mass of 20 kg. If the dog is pushed across the ice with a force of 40 N, what is its acceleration?
olasank [31]

Answer:

The acceleration is 2 m/s2.

Explanation:

We calculate the acceleration (a), with the data of mass (m) and force (F), through the formula:

F = m x a  ---> a= F/m

a = 40 N/20 kg                   <em>  1N= 1 kg x m/s2</em>

a= 40 kgx m/s2/ 20 kg

<em>a= 2 m/s2</em>

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3 years ago
A man wishes to pull a crate 15m across a rough floor by exerting a force of 100 N. The
Darina [25.2K]

Answer:

option (E) is correct.

Explanation:

Work done is defined as the product of force and the distance in the direction of force.

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Coefficient of friction, = 0.25

distance = 15 m

So, net force F = f - friction force

F = 100 - 0.25 x m g

Work = (100 - 0.25 mg) x d cosθ

For minimum work, the angle should be maximum.

So, the value of θ is 76°.

thus, option (E) is correct.

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3 years ago
What is the need of force in our life​
melamori03 [73]

Answer:

A force is a push or a pull and it affects our daily lives because without force,people would not be able to open and close stuff or lift up our arms or legs .....or anything, for that matter.

Explanation:

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3 years ago
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