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lisabon 2012 [21]
3 years ago
12

How can you which molecule is positive and negative in a dipole-dipole relationship?

Chemistry
1 answer:
marysya [2.9K]3 years ago
5 0
Dipole interactions are observed in covalent bonds. In ionic bonding, permanent transfer of electrons occurs and due to this dipole-dipole interactions are not observed. In covalent bonding, electron cloud is shared between 2 atoms. If this electron cloud is not shared equally between them, polarities are formed in a molecule. And hence we say that the molecule is polar. For a molecule to be polar, there should be electronegativity difference between them. Atom with greater electronegative attracts electron cloud more towards itself whereas atom with lesser electronegative attracts electron cloud less. But there is no permanent transfer of electrons. Due to this electronegativity differences, atom with more electronegative gains partial negative charge and atom with lesser electronegative value gains partial positive charge. The charge is partial because there is no complete transfer of electrons.
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A 25.0 ml sample of 0.723 m hclo4 is titrated with a 0.27303 m koh solution. the h3o+ concentration after the addition of 66.2 m
tia_tia [17]
This doesn't need an ICE chart. Both will fully dissociate in water.

Assume HClO4 and KOH reacts with one another. All you need to do is determine how much HClO4 will remain after the reaction. Calculate pH.

Step 1:

write out balanced equation for the reaction

HClO4+KOH ⇔ KClO4 + H2O

the ratio of HClO4 to KOH is going to be 1:1. Each mole of KOH we add will fully react with 1 mole of HClO4

Step 2:

Determining the number of moles present in HClO4 and KOH

Use the molar concentration and the volume for each:
25 mL of 0.723 M HClO4

Covert volume from mL into L:
25 mL * 1L/1000mL = 0.025 L

Remember:

M = moles/L so we have 0.025 L of 0.723 moles/L HClO4

Multiply the volume in L by the molar concentration to get:

0.025L x 0.723mol/L = 0.0181 moles HClO4.

Add 66.2 mL KOH with conc.=0.273M
66.2mL*1L/1000mL = .0662 L
.0662L x 0.273mol/L = 0.0181 moles KOH

Step 3:

Determine how much HClO4 remains after reacting with the KOH.

Since both reactants fully dissociate and are used in a 1:1 ratio, we just subtract the number of moles of KOH from the number of moles of HClO4:

moles HClO4 = 0.0181; moles KOH = 0.0181, so 0.0181-0.0181 = 0

This means all of the HClO4 is used up in the reaction.

If all of the acid is fully reacted with the base, the pH will be neutral = 7.

Determine the H3O+ concentration:

pH = -log[H3O+]; [H3O+] = 10-pH = 10-7

The correct answer is 1.0x10-7.
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Explanation:

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