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lisabon 2012 [21]
3 years ago
12

How can you which molecule is positive and negative in a dipole-dipole relationship?

Chemistry
1 answer:
marysya [2.9K]3 years ago
5 0
Dipole interactions are observed in covalent bonds. In ionic bonding, permanent transfer of electrons occurs and due to this dipole-dipole interactions are not observed. In covalent bonding, electron cloud is shared between 2 atoms. If this electron cloud is not shared equally between them, polarities are formed in a molecule. And hence we say that the molecule is polar. For a molecule to be polar, there should be electronegativity difference between them. Atom with greater electronegative attracts electron cloud more towards itself whereas atom with lesser electronegative attracts electron cloud less. But there is no permanent transfer of electrons. Due to this electronegativity differences, atom with more electronegative gains partial negative charge and atom with lesser electronegative value gains partial positive charge. The charge is partial because there is no complete transfer of electrons.
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1. The heat of fusion for the ice-water phase transition is 335 kJ/kg at 0°C and 1 bar. The density of water is 1000 kg/m3 at th
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Answer:

Expression for the change of melting temperature with pressure..> T₂ = T₁exp(-(P₂-P₁)/(3.61x10⁹ Pa), Freezing Point = 0°C

Explanation:

Derivation from state postulate

Using the state postulate, take the specific entropy,  , for a homogeneous substance to be a function of specific volume  and temperature  .

ds = (partial s/partial v)(t) dv + (partial s/partial T)(v) dT

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Using the appropriate Maxwell relation gives

ds = (partial P/partial T)(v) dv

s(β) – s(aplαha) = dP/dT (v(β) – v(α))

dP/dT = s(β) – s(α)/v(β) – v(α) = Δs/Δv

Here Δs and Δv are respectively the change in specific entropy and specific volume from the initial phase α to the final phase β.

For a closed system undergoing an internally reversible process, the first law is

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Using the definition of specific enthalpy, h and the fact that the temperature and pressure are constant, we have

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After substitution of this result into the derivative of the pressure, one finds

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<u>This last equation is the Clapeyron equation.</u>

a)

(dP/dT) = dH/TdV => dP/dlnT = dH/dV

=> dP/dlnT = dH/dV = [H(liquid) - H(solid)]/[V(liquid) - V(solid)]

= [335,000 J/kg]/[1000⁻¹ - 915⁻¹ m³/kg]

= -3.61x10⁹ J/m³ = -3.61x10⁹ Pa

=> P₂ = P₁ - 3.61x10⁹ ln(T₂/T₁) Pa

or

T₂ = T₁exp(-(P₂-P₁)/(3.61x10⁹ Pa)

b) if the pressure in Denver is 84.6 kPa:

T₂(freezing) = 273.15exp[-(84,600-100,000)/(3.61x10⁹)]

≅ 273.15 = 0°C T₁(freezing) essentially no change

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