Answer:
1.332 meters per second. // 2.664 meters per second.
Explanation:
the slower person moved 33.3 meters, and the faster person moved 66.6 meters.
the slower person is moving 33.3 meters in 25 seconds, while the other person is moving 66.6 meters in 25 seconds
slower person moved 33.3/25 = 1.332 meters per second.
faster person moved 66.6/25 = 2.664 meters per second.
Hello!
The chemical reaction for the dissolving of calcium fluoride is the following:
CaF₂(s) ⇄ Ca⁺²(aq) + 2F⁻(aq)
In this reaction, and according to Le Chatelier's principle, the action that would shift this reaction away from solid calcium fluoride and towards the dissolved ions is the removing of fluoride ions.
Le Chatelier's principle states that in an equilibrium reaction, the system would shift in the opposite direction of the changes. If we remove fluoride ions from the system, it will shift towards the formation of more fluoride ions by dissolving more Calcium Fluoride to achieve equilibrium again.
Have a nice day!
Answer : The rate of change of the total pressure of the vessel is, 10.5 torr/min.
Explanation : Given,
=21 torr/min
The balanced chemical reaction is,

The rate of disappearance of
= ![-\frac{1}{2}\frac{d[NO]}{dt}](https://tex.z-dn.net/?f=-%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BNO%5D%7D%7Bdt%7D)
The rate of disappearance of
= ![-\frac{d[Cl_2]}{dt}](https://tex.z-dn.net/?f=-%5Cfrac%7Bd%5BCl_2%5D%7D%7Bdt%7D)
The rate of formation of
= ![\frac{1}{2}\frac{d[NOCl]}{dt}](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BNOCl%5D%7D%7Bdt%7D)
As we know that,
=21 torr/min
So,
![-\frac{d[Cl_2]}{dt}=-\frac{1}{2}\frac{d[NO]}{dt}](https://tex.z-dn.net/?f=-%5Cfrac%7Bd%5BCl_2%5D%7D%7Bdt%7D%3D-%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BNO%5D%7D%7Bdt%7D)
![\frac{d[Cl_2]}{dt}=\frac{1}{2}\times 21torr/min=10.5torr/min](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BCl_2%5D%7D%7Bdt%7D%3D%5Cfrac%7B1%7D%7B2%7D%5Ctimes%2021torr%2Fmin%3D10.5torr%2Fmin)
And,
![\frac{1}{2}\frac{d[NOCl]}{dt}=\frac{1}{2}\frac{d[NO]}](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BNOCl%5D%7D%7Bdt%7D%3D%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BNO%5D%7D)
![\frac{d[NOCl]}{dt}=\frac{d[NO]}=21torr/min](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BNOCl%5D%7D%7Bdt%7D%3D%5Cfrac%7Bd%5BNO%5D%7D%3D21torr%2Fmin)
Now we have to calculate the rate change.
Rate change = Reactant rate - Product rate
Rate change = (21 + 10.5) - 21 = 10.5 torr/min
Therefore, the rate of change of the total pressure of the vessel is, 10.5 torr/min.
Answer : (b) The rate law expression for the reaction is:
![\text{Rate}=k[SO_2]^2[O_2]](https://tex.z-dn.net/?f=%5Ctext%7BRate%7D%3Dk%5BSO_2%5D%5E2%5BO_2%5D)
Explanation :
Rate law : It is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.
The general reaction is:

The general rate law expression for the reaction is:
![\text{Rate}=k[A]^a[B]^b](https://tex.z-dn.net/?f=%5Ctext%7BRate%7D%3Dk%5BA%5D%5Ea%5BB%5D%5Eb)
where,
a = order with respect to A
b = order with respect to B
R = rate law
k = rate constant
and
= concentration of A and B reactant
Now we have to determine the rate law for the given reaction.
The balanced equations will be:

In this reaction,
and
are the reactants.
The rate law expression for the reaction is:
![\text{Rate}=k[SO_2]^2[O_2]^1](https://tex.z-dn.net/?f=%5Ctext%7BRate%7D%3Dk%5BSO_2%5D%5E2%5BO_2%5D%5E1)
or,
![\text{Rate}=k[SO_2]^2[O_2]](https://tex.z-dn.net/?f=%5Ctext%7BRate%7D%3Dk%5BSO_2%5D%5E2%5BO_2%5D)