A hydrocarbon sample was burned in a bomb calorimeter. The temperature of the calorimeter and the 1.00 kg of water rose from 20.
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Answer:
401.17 K is the minimum temperature at which the reaction will become spontaneous under standard state conditions.
Explanation:
The expression for the standard change in free energy is:
Where,
is the change in the Gibbs free energy.
T is the absolute temperature. (T in kelvins)
is the enthalpy change of the reaction.
is the change in entropy.
Given at:-
Temperature = 25.0 °C
The conversion of T( °C) to T(K) is shown below:
T(K) = T( °C) + 273.15
So,
T₁ = (25.0 + 273.15) K = 298.15 K
= 128.9 kJ/mol
= 33.1 kJ/mol
Applying in the above equation, we get as:-
= 0.32131 kJ/Kmol
So, For reaction to be spontaneous,
Thus, For minimum temperature:-
<u>Hence, 401.17 K is the minimum temperature at which the reaction will become spontaneous under standard state conditions.</u>