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likoan [24]
3 years ago
14

Please help ASAP.

Chemistry
1 answer:
Lady_Fox [76]3 years ago
8 0
Looked it up for you. Hope this helps

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Your job is to determine the concentration of ammonia in a commercial window cleaner. In the titration of a 25.0 mL sample of th
ruslelena [56]

Answer:

The initial concentration of ammonia is 0.14 M and the pH of the solution at equivalence point is 5.20

<u>Explanation:</u>

To calculate the number of moles for given molarity, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}      .....(1)

Molarity of HCl solution = 0.164 M

Volume of solution = 23.8 mL = 0.0238 L    (Conversion factor:  1 L = 1000 mL)

Putting values in equation 1, we get:

0.164M=\frac{\text{Moles of HCl}}{0.0238L}\\\\\text{Moles of HCl}=(0.146mol/L\times 0.0238L)=0.0035mol

The chemical equation for the reaction of ammonia and HCl follows:

NH_3+HCl\rightarrow NH_4^++Cl^-

By Stoichiometry of the reaction:

1 mole of HCl reacts with 1 mole of ammonia

So, 0.0035 moles of HCl will react with = \frac{1}{1}\times 0.0035=0.0035mol of ammonia

  • Calculating the initial concentration of ammonia by using equation 1:

Moles of ammonia = 0.0035 moles

Volume of solution = 25 mL = 0.025 L

Putting values in equation 1, we get:

\text{Initial concentration of ammonia}=\frac{0.0035mol}{0.025L}=0.14M

By Stoichiometry of the reaction:

1 mole of ammonia produces 1 mole of ammonium ion

So, 0.0035 moles of ammonia will react with = \frac{1}{1}\times 0.0035=0.0035mol of ammonium ion

  • Calculating the concentration of ammonium ion by using equation 1:

Moles of ammonium ion = 0.0035 moles

Volume of solution = [23.8 + 25] mL = 48.8 mL = 0.0488 L

Putting values in equation 1, we get:

\text{Molarity of ammonium ion}=\frac{0.0035mol}{0.0488L}=0.072M

  • To calculate the acid dissociation constant for the given base dissociation constant, we use the equation:

K_w=K_b\times K_a

where,

K_w = Ionic product of water = 10^{-14}

K_a = Acid dissociation constant

K_b = Base dissociation constant = 1.8\times 10^{-5}

10^{-14}=1.8\times 10^{-5}\times K_a\\\\K_a=\frac{10^{-14}}{1.8\times 10^{-5}}=5.55\times 10^{-10}

The chemical equation for the dissociation of ammonium ion follows:

NH_4^+\rightarrow NH_3+H^+

The expression of K_a for above equation follows:

K_a=\frac{[NH_3][H^+]}{[NH_4^+]}

We know that:

[NH_3]=[H^+]=x

[NH_4^+]=0.072M

Putting values in above expression, we get:

5.55\times 10^{-10}=\frac{x\times x}{0.072}\\\\x=6.32\times 10^{-6}M

To calculate the pH concentration, we use the equation:

pH=-\log[H^+]

We are given:

[H^+]=6.32\times 10^{--6}M

pH=-\log (6.32\times 10^{-6})\\\\pH=5.20

Hence, the initial concentration of ammonia is 0.14 M and the pH of the solution at equivalence point is 5.20

5 0
3 years ago
The net ionic equation for formation of an aqueous solution of nii2 accompanied by evolution of co2 gas via mixing solid nico3 a
Ann [662]

Answer:

NiCO3 (s) + 2H+ (aq) → H2O (l) + CO2 (g) + Ni2+ (aq)

Explanation:

To write the complete ionic equation:

1. Start with a balanced molecular equation.

2. Break all soluble strong electrolytes (compounds with (aq) beside them) into their ions

3. indicate the correct formula and charge of each ion

4. indicate the correct number of each ion

5. write (aq) after each ion

6. Bring down all compounds with (s), (l), or (g) unchanged.

8 0
3 years ago
Which of these are ionic compounds? Check all that apply.
SIZIF [17.4K]
I think the correct answers from the choices listed above are the first, third and the last option. Ionic compounds are compounds that dissociates into ions when in aqueous solution. From the list, NH4Cl, KF and MgO are the ionic compounds. Hope this answers the question.
5 0
3 years ago
Read 2 more answers
What is the correct formula for xenon hexafluoride
LiRa [457]
Formula for Xenon hexafluoride is XeF6
4 0
3 years ago
Read 2 more answers
Which of these describes an endothermic process?
Phoenix [80]
The third one down: "When barium hydroxide is mixed with ammonium chloride, ice crystals form on the outside of the container."

This is because an endothermic reaction [process] takes in more energy than it releases. Therefore because a decrease in energy leads to a decrease in temperature, the ice crystals forming show that it must be a endothermic reaction [process].

Hope this helps! :)
AJ
3 0
3 years ago
Read 2 more answers
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