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sveticcg [70]
3 years ago
15

Sewage and industrial pollutants dumped into a body of water can reduce the dissolved oxygen concentration and adversely affect

aquatic species. In one study, weekly readings are taken from the same location in a river over a two-month period. The week 3 measurement in the data set is suspected of being an outlier.
True or False: According to the Q test, the value at week 3 can be rejected at the 95% confidence level.
Week Dissolved O2 (ppm)
1 4.9
2 5.1
3 5.6
4 4.3
5 4.7
6 4.9
7 4.5
8 5.1
Chemistry
1 answer:
MArishka [77]3 years ago
7 0

Answer:

FALSE

Since 0.385 < 0.526, the value for week 3 is accepted.

Explanation:

Qexp = (|Xq - Xₙ₋₁|)/w

where Xq is the suspected outlier; Xₙ₋₁ is the next nearest data point; w is the range of data

First, the data are arranged in decreasing order, from highest to lowest:

3. 5.6

2. 5.1

8. 5.1

1. 4.9

6. 4.9

5. 4.7

7. 4.5

4. 4.3

Xq = 5.6; Xₙ₋₁ = 5.1; w = 5.6 - 4.3 = 1.3

Qexp = (|5.6 - 5.1|)/1.3 = 0.385

From tables, at 95% confidence level, for n = 8, Qcrit = 0.526

Since 0.385 < 0.526, the value for week 3 is accepted.

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In acidic aqueous solution, the purple complex ion Co(NH3)5Br2+ undergoes a slow reaction in which the bromide ion is replaced b
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Answer:

A) 0.065 M is its molarity after a reaction time of 19.0 hour.

B) In 52 hours [Co(NH_3)5Br]^{2+} will react 69% of its initial concentration.

Explanation:

Co(NH_3)_5(H_2O)_3+[Co(NH_3)5Br]^{2+}(Purple)(aq)+H_2O(l)\rightarrow [Co(NH_3)_5(H_2O)]^{3+}(Pinkish-orange)(aq)+Br^-(aq)

The reaction is first order in [Co(NH_3)5Br]^{2+}:

Initial concentration of [Co(NH_3)5Br]^{2+}= [A_o]=0.100 M

a) Final concentration of [Co(NH_3)5Br]^{2+} after 19.0 hours= [A]

t = 19.0 hour = 19.0 × 3600 seconds ( 1 hour = 3600 seconds)

Rate constant of the reaction = k = 6.3\times 10^{-6} s^{-1}

The integrated law of first order kinetic is given as:

[A]=[A_o]\times e^{-kt}

[A]=0.100 M\times e^{-6.3\times 10^{-6} s^{-1}\times 19.0\times 3600 s}

[A]=0.065 M

0.065 M is its molarity after a reaction time of 19.0 h.

b)

Initial concentration of [Co(NH_3)5Br]^{2+}= [A_o]=x

Final concentration of [Co(NH_3)5Br]^{2+} after t = [A]=(100\%-69\%) x=31\%x=0.31x

Rate constant of the reaction = k = 6.3\times 10^{-6} s^{-1}

The integrated law of first order kinetic is given as:

[A]=[A_o]\times e^{-kt}

0.31x=x\times e^{-6.3\times 10^{-6} s^{-1}\t}

t = 185,902.06 s = \frac{185,902.06 }{3600} hour = 51.64 hours ≈ 52 hours

In 52 hours [Co(NH_3)5Br]^{2+} will react 69% of its initial concentration.

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