The structure of the alkyl bromides used in a malonic ester synthesis of ethyl 2-methyl-4-pentenoate are as drawn in the attached image.
<h3>Ethyl 2-methyl-4-pentenoate by Malonic ester synthesis.</h3>
The malonic ester synthesis is a chemical reaction characterized by the alkylation of diethyl malonate or a similar ester of malonic acid at the carbon alpha (directly adjacent) to both carbonyl groups, and subsequently converted to a substituted acetic acid.
Hence, it follows from the structure of Ethyl 2-methyl-4-pentenoate that the alkyl bromides used are Ethyl bromide and methyl bromide.
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Answer:
A) An ionic bond is much stronger than most covalent bonds.
Explanation:
D) Ionic compounds have high melting points causing them to be solid at room temperature, and conduct electricity when dissolved in water. Covalent compounds have low melting points and many are liquids or gases at room temperature.
C) An ionic bond is a type of chemical bond formed through an electrostatic attraction between two oppositely charged ions. Ionic bonds are formed between a cation, which is usually a metal, and an anion, which is usually a nonmetal. A covalent bond involves a pair of electrons being shared between atoms.
A) Covalent bonds are stronger if you compare with ionic molecules, because their molecular orbital overlap is bigger. However, ionic molecules form lattices, thus the energy to break this lattice bond is stronger hence the ionic bond is stronger.
Answer:
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Explanation:
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__5___SiO2 + ___2___CaC2 → __5___Si + ____2___CaO + __4___CO2
Answer:
a) ammonium ion
b) amide ion
Explanation:
The order of decreasing bond angles of the three nitrogen species; ammonium ion, ammonia and amide ion is NH4+ >NH3> NH2-. Next we need to rationalize this order of decreasing bond angles from the valence shell electron pair repulsion (VSEPR) theory perspective.
First we must realize that all three nitrogen species contain a central sp3 hybridized carbon atom. This means that a tetrahedral geometry is ideally expected. Recall that the presence of lone pairs distorts molecular structures from the expected geometry based on VSEPR theory.
The amide ion contains two lone pairs of electrons. Remember that the presence of lone pairs causes greater repulsion than bond pairs on the outermost shell of the central atom. Hence, the amide ion has the least H-N-H bond angle of about 105°.
The ammonia molecule contains one lone pair, the repulsion caused by one lone pair is definitely bless than that caused by two lone pairs of electrons hence the bond angle of the H-N-H bond in ammonia is 107°.
The ammonium ion contains four bond pairs and no lone pair of electrons on the outermost nitrogen atom. Hence we expect a perfect tetrahedron with bond angle of 109°.
It takes 33.4 s for the concentration of A to fall to one-fourth of its original value.
A <em>half-life</em> is the time it takes for the concentration to fall to half its original value.
Assume the initial concentration is 1.00 mol/L. Then,

The concentration drops to one-fourth of its initial value in two half-lives.
∴ Time = 2 × 16.7 s = 33.4 s