Answer:
1: At temperatures below 542.55 K
2: At temperatures above 660 K
Explanation:
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In this case, according to the thermodynamic definition of the Gibbs free energy, it is possible to write the following expression:
Whereas ΔG=0 for the spontaneous transition. In such a way, we proceed as follows:
1:
It means that at temperatures lower than 542.55 K the reaction will be spontaneous.
2:
It means that at temperatures higher than 660 K the reaction will be spontaneous.
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Answer:
a. 0.5 mol
b. 1.5 mol
c. 0.67
Explanation:
Fe3+ + SCN- -----> [FeSCN]2+
a. The ratio of the product to Fe3+ is 1:1. Meaning that if 0.5 mol of product was produced up then 0.5 mol of Fe3+ was used. Leaving 0.5 mol remaining at equilibrium
b. The ratio of the product to SCN= is 1:1. Meaning that if 0.5 mol of product was produced up then 0.5 mol of SCN- was used. Leaving 1.5 mol remaining at equilibrium
c. KC = 0.5/(0.5*1.5) = 0.67
The fusion on water is an enxothermic change but at this temp, the temp-entropy product is outweighed by the change in enthalpy.
Answer:
See explanation.
Explanation:
Since potassium tert-butoxide is a strong bulky base, we expect that an elimination reaction predominates.
This reaction is expected to occur by E2 mechanism. The cis isomer of 1-bromo-4-tert-butylcyclohexane is known to react faster by E2 mechanism because it fulfills the anticoplanar arrangement required for for E2 mechanism, where the leaving group and adjacent proton must be anti to each other and in the same plane. The trans isomer can not fulfill this requirement.
