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bogdanovich [222]
3 years ago
9

Question 9 rank the effective nuclear charge z * experienced by a valence electron in each of these atoms:

Chemistry
1 answer:
AlexFokin [52]3 years ago
7 0
To rank the effective nuclear charge Z* experienced by a valence electrons of a set of atoms that belong to a same period, you only need to apply the rule of trend: it increases as you move from left to right in the period.

So, lets do it for these atoms: P,  Al, Si, Cl

The belong to a same period and the order is Al, Si, P, Cl (just see a periodic table). So the rank is Al < Si < P < Cl

Now, lets do it for these atoms:, Be, Ne, O, C

They belong to the second period. The order is Be, C, O, Ne

So, the rank is Be < C < O < Ne.


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Answer:

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Explanation:

Using the derived expression from Arrhenius Equation

In \ (\frac{k_2}{k_1}) = \frac{E_a}{R}(\frac{T_2-T_1}{T_2*T_1})

Given that:

time t_1 = 8.3 days = (8.3 × 24 ) hours = 199.2 hours

time t_2 = 10.6 hours

Temperature T_1 = 0° C = (0+273 )K = 273 K

Temperature T_2 = 30° C = (30+ 273) = 303 K

Rate = 8.314 J / mol

Since (\frac{k_2}{k_1}=\frac{t_2}{t_1})

Then we can rewrite the above expression as:

In \ (\frac{t_2}{t_1}) = \frac{E_a}{R}(\frac{T_2-T_1}{T_2*T_1})

In \ (\frac{199.2}{10.6}) = \frac{E_a}{8.314}(\frac{303-273}{273*303})

2.934 = \frac{E_a}{8.314}(\frac{30}{82719})

2.934 = \frac{30E_a}{687725.766}

30E_a = 2.934 *687725.766

E_a = \frac{2.934 *687725.766}{30}

E_a =67255.58 \ J/mol

E_a =67.2 \ kJ/mol

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