Answer:
ΔH rxn = -1010 kJ/molC₂H₂
Explanation:
To obtain the enthalpy change for a reaction from bond energies what we do is to make an inventory of the bonds broken and formed for the balanced chemical reaction:
C₂H₂ + 5/2O₂ ⇒ 2CO₂ + H₂O
Bond Broken Bonds Formed
2 C-H + 1 C≡C + 5/2 O=O 4C=O + 2 H-O
Enthalpy bonds broken:
2 mol (456 kJ/mol)+ 1 mol (962 kJ/mol) + 5/2 mol (499 kJ/mol) = 3121.5 kJ
Enthalpy bond formed:
4 mol (802 kJ/mol) + 2 mol (462 kJ/mol) = 4132.0 kJ
ΔH rxn = H broken - H formed = 3121.5 kJ - 4132.0 kJ = - 1010 kJ (per mol C₂H₂ )
Answer:
Rate = k . [B]² . [C]
Explanation:
The dependence of the reaction rate on the concentration of the reactants is given by the reaction order of each one, as shown in the rate equation.
![Rate=k.[A]^{x} .[B]^{y} .[C]^{z}](https://tex.z-dn.net/?f=Rate%3Dk.%5BA%5D%5E%7Bx%7D%20.%5BB%5D%5E%7By%7D%20.%5BC%5D%5E%7Bz%7D)
where,
k is the rate constant
x, y, z are the reaction orders.
- <em>The rate of reaction is not affected by changing the concentration of species A.</em> This means that the reaction order for A is x = 0 since when its concentration changes, the rate stays the same.
- <em>Leaving all other factors identical, doubling the concentration of species B increases the rate by a factor of 4.</em> This means that the reaction order for B is y = 2, so when the concentration is doubled, the new rate is 2² = 4 times the initial rate.
- The rate of the reaction is linearly dependent on the concentration of C. This means that the reaction order for C is z = 1, that is, a linear dependence.
All in all, the rate equation is:
Rate = k . [B]² . [C]
Answer:
It is higher.
Explanation:
The amplitude of a wave that carries more energy is usually higher.
The energy carried by a wave is related to the amplitude in such a manner that it is proportional to the square amplitude.
Amplitude is the maximum vertical displacement of a wave moving along its path.
- Energy of wave and its amplitude are directly proportional to one another.
- If the energy of wave is doubled, the amplitude is quadrupled.
- So, the higher the energy of a wave, the more its amplitude.