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kakasveta [241]
3 years ago
8

How does the value of kc in n2o4(g)⇋2no2(g) kc=[no2]2[n2o4] depend on the starting concentrations of no2 and n2o4?

Chemistry
1 answer:
Vlad [161]3 years ago
8 0
<h3><u>Answer;</u></h3>

The value of Kc does not depend on starting concentrations.

<h3><u>Explanation;</u></h3>
  • <em><u>At constant temperature, changing the equilibrium concentration does not affect the equilibrium constant, because the rate constants are not affected by the concentration changes. </u></em>
  • When the concentration of one of the participants is changed, the concentration of the others vary in such a way as to maintain a constant value for the equilibrium constant.
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Let's consider the following generic reaction

A + B + C ⇒ Products

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This reaction is first order in A, second order in B, and zero order in C. The rate law is:

r = k × [A]¹ × [B]² × [C]⁰

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How do solve for #13?What is the boiling point of a solution made by dissolving 1.0000 mole of sucrose in 1.0000 kg of water?
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What is the boiling point of a solution made by dissolving 1.0000 mole of sucrose in 1.0000 kg of water?

The change in Boiling Point of water can be calculated using this formula:

ΔTb = i * Kb * m

Where i is the van't hoff factor (the number of particles or ions), the kb is a constant (boiling point elevation constant) and m is the molality of the solution.

The kb for water is always 0.515 °C/m. Kb = 0.515 °C/m

The value for i in this case is 1. Since sucrose is a covalent compound and it doesn't dissociate into ions. i = 1

The molal concentration of the solution can be found using this formula:

molality = moles of sucrose/kg of water

molality = 1.000 mol / 1.000 kg of water

molality = 1 m

Now that we know all the values, we can use the formula to find the change in the boiling point of water:

ΔTb = i * Kb * m

ΔTb = 1 * 0.515 °C/m * 1 m

ΔTb = 0.515 °C

Finally, we are asked for the boiling point of the solution, not the change. The boiling point of water at atmospheric pressure is 100.00 °C. If the boiling point rises 0.515 °C when we prepare the solution. The boiling point of the solution is:

Boiling point solution = Boiling point of water + ΔTb

Boiling point solution = 100.000 °C + 0.515 °C

Boiling point solution = 100.515 °C

Answer: The boiling point of the solution is 100.515 °C.

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