Answer: 4.18925 kJ heat is needed to convert 25.0 g of solid ethanol at -135 °C to liquid ethanol at -50°C.
Explanation:
Temperature of Solid
Melting temperature of Solid 
Temperature of liquid 
Specific heats of solid ethanol = 0.97 J/gK
Specific heats of liquid ethanol = 2.3 J/gK
Heat required to melt the the 25 g solid
at 159 K
= 159 K - 138 K = 21 K

Heat required to melt and raise the temperature of
upto 223 K
= 223 K - 159 K = 64 K

Total heat to convert solid ethanol to liquid ethanol at given temperature :
(1kJ=1000J)
Hence, 4.18925 kJ of heat will be required to convert 25.0 g of solid ethanol at -135 °C to liquid ethanol at -50°C.
Cu + S ---> CuS
by reaction 1 mol 1 mol
from the problem 0.25 mol 0.25 mol
0.25 mol Cu
<span>The atoms or molecules attain enough kinetic energy to overcome any intermolecular attractions they have. Since there are no longer any attractive forces between the particles, they are free to drift away into space. The same sort of thing happens in ordinary evaporation, but only at the surface. </span>