It means the relationship between two systems connected only by a diathermic wall.
Answer:
that is true. because reversible react is take place in forward and backward reaction
Answer:
b) pH = 9.25
Explanation:
- NH4+(aq) + H2O(l) ↔ NH3(aq) + H3O+(aq)
- NH3 + H2O ↔ NH4+ + OH-
- 2 H2O ↔ H3O+ + OH-
⇒ Kb = [ NH4+ ] * [ OH- ] / [ NH3 ] = 1.86 E-5......from literature
mass balance NH4+:
⇒ M NH4+ = [ NH4+ ] - [ OH- ]
∴ [ NH3 ] ≅ M NH4+ = 0.26 M
⇒ Kb = (( 0.26 + [ OH- ] )) * [ OH- ] / 0.26 = 1.86 E-5
⇒ 0.26 [ OH-] + [ OH- ]² = 4.836 E-6
⇒ [ OH- ]² + 0.26 [ OH- ] - 4.836 E-6 = 0
⇒ [ OH- ] = 1.859 E-5 M
⇒ pOH = - Log ( 1.859 E-5 )
⇒ pOH = 4.7305
⇒ pH = 14 - pOH = 9.269
Answer :
The Nernst equation :
![E_{cell}=E^o_{cell}-\frac{2.303RT}{nF}\log \frac{[Anode]}{[Cathode]}](https://tex.z-dn.net/?f=E_%7Bcell%7D%3DE%5Eo_%7Bcell%7D-%5Cfrac%7B2.303RT%7D%7BnF%7D%5Clog%20%5Cfrac%7B%5BAnode%5D%7D%7B%5BCathode%5D%7D)
where,
= standard cell potential
n = number of electrons in oxidation-reduction reaction
F = Faraday constant = 96500 C
R= gas constant = 8.314 J/Kmol
T = temperature
[Anode] = anodic ion concentration
[Cathode] = cathodic ion concentration
