Reaction of
Acyl Halides with
Grignard reagent results in the formation of
Ketones in first step. While in second step reaction of Grignard reagent with Ketones results in the formation of
Tertiary Alcohols.
If you want to
stop the reaction at
Ketone stage then you are required to use another
mild reactive organometallic compound. In our case we will use Organocuprates.
Organocuprates are also known as Gilman Reagents. These reagents does not add to ketones, aldehydes and esters but they can add to acid halides to produce Ketones.
When an electron passes through the magnetic field of a horseshoe magnet, the electron's direction is changed.
Path of an electron in a magnetic field
The force (F) on wire of length L carrying a current I in a magnetic field of strength B is given by the equation:
F = BIL
But Q = It and since Q = e for an electron and v = L/t you can show that :
Magnetic force on an electron = BIL = B[e/t][vt] = Bev where v is the electron velocity
In a magnetic field the force is always at right angles to the motion of the electron (Fleming's left hand rule) and so the resulting path of the electron is circular.
Therefore :
Magnetic force = Bev = mv2/r = centripetal force
v = [Ber]/m
and so you can see from these equations that as the electron slows down the radius of its orbit decreases.
If the electron enters the field at an angle to the field direction the resulting path of the electron (or indeed any charged particle) will be helical. Such motion occurs above the poles of the Earth where charges particles from the Sun spiral through the Earth's field to produce the aurorae.
To learn more about electron : brainly.com/question/860094
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Answer:
175 kJ
Explanation:
Activation energy can be defined as the potential energy that is needed to change reactants to products. This is the minimum energy required for the chemical reaction to take place. Thus, using the given figure:
Activation energy = activation complex - reactant energy
In the given figure, activation complex = 400 kJ
reactant energy = 225 kJ
Therefore:
Activation energy = 400 - 225 = 175 kJ
Explanation:
the tip of a growing plant contains special rapidly diving cells called apical meristem ,these cells are responsible for increase in the length of the plant . if we cut out these cells ,length growth of the plant will be stunned as these cells are not present anyplace else.
<u>Answer:</u> The equilibrium concentration of water is 0.597 M
<u>Explanation:</u>
Equilibrium constant in terms of concentration is defined as the ratio of concentration of products to the concentration of reactants each raised to the power their stoichiometric ratios. It is expressed as 
For a general chemical reaction:
The expression for 
is written as:
![K_{c}=\frac{[C]^c[D]^d}{[A]^a[B]^b}](https://tex.z-dn.net/?f=K_%7Bc%7D%3D%5Cfrac%7B%5BC%5D%5Ec%5BD%5D%5Ed%7D%7B%5BA%5D%5Ea%5BB%5D%5Eb%7D)
The concentration of pure solids and pure liquids are taken as 1 in the expression.
For the given chemical reaction:
The expression of 
for above equation is:
![K_c=\frac{[H_2O]^2}{[H_2S]^2\times [O_2]}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BH_2O%5D%5E2%7D%7B%5BH_2S%5D%5E2%5Ctimes%20%5BO_2%5D%7D)
We are given:
![[H_2S]_{eq}=0.671M](https://tex.z-dn.net/?f=%5BH_2S%5D_%7Beq%7D%3D0.671M)
![[O_2]_{eq}=0.587M](https://tex.z-dn.net/?f=%5BO_2%5D_%7Beq%7D%3D0.587M)
Putting values in above expression, we get:
![1.35=\frac{[H_2O]^2}{(0.671)^2\times 0.587}](https://tex.z-dn.net/?f=1.35%3D%5Cfrac%7B%5BH_2O%5D%5E2%7D%7B%280.671%29%5E2%5Ctimes%200.587%7D)
![[H_2O]=\sqrt{(1.35\times 0.671\times 0.671\times 0.587)}=0.597M](https://tex.z-dn.net/?f=%5BH_2O%5D%3D%5Csqrt%7B%281.35%5Ctimes%200.671%5Ctimes%200.671%5Ctimes%200.587%29%7D%3D0.597M)
Hence, the equilibrium concentration of water is 0.597 M
