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Wittaler [7]
2 years ago
5

. Which substance is the limiting reactant when 2 g of S reacts with 3 g of O2 and 4 g of NaOH according to the following chemic

al equation: 2 S (s) + 3 O2 (g) + 4 NaOH (aq) → 2 Na2SO4 (aq) + 2 H2O (l) a) S (s) b) O2 (g) c) NaOH (aq) d) none of these substances is the limiting reactant.
Chemistry
1 answer:
Ksivusya [100]2 years ago
3 0

Answer:

S is the limiting reagent.

Explanation:

To find the limiting reactant we must first write the balanced chemical reaction. It must be correctly balanced so that we can find the proper mole ratios.

2 S (s) + 3 O2 (g) + 4 NaOH (aq) → 2 Na2SO4 (aq) + 2 H2O (l)

After this we will convert our measurements to moles. For mass we do this by dividing by the molar mass.

2g ÷ 32.06 = 0.06238mol S

3g ÷ 32.00 = 0.09375mol O₂

Now that we have the moles of each of the reactants, we can multiply them by their mole ratio with a reactant.

0.06238mol S × 2/2 = 0.06238mol H2O

0.09375mol O₂ × 2/3 = 0.06250mol H2O

S is our limiting reagent because it makes the smaller amount of moles.

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<u>Answer:</u> The \Deltas H^o_{formation} for the reaction is -1406.8 kJ.

<u>Explanation:</u>

Hess’s law of constant heat summation states that the amount of heat absorbed or evolved in a given chemical equation remains the same whether the process occurs in one step or several steps.

According to this law, the chemical equation is treated as ordinary algebraic expressions and can be added or subtracted to yield the required equation. This means that the enthalpy change of the overall reaction is equal to the sum of the enthalpy changes of the intermediate reactions.

The chemical reaction for the formation reaction of AlCl_3 is:

2Al(s)+3Cl_2(g)\rightarrow 2AlCl_3 (s)    \Delta H^o_{formation}=?

The intermediate balanced chemical reaction are:

(1) HCl(g)\rightarrow HCl(aq.)    \Delta H_1=-74.8kJ    ( ×  6)

(2) H_2(g)+Cl_2(g)\rightarrow 2HCl(g)    \Delta H_2=-185kJ     ( ×  3)

(3) AlCl_3(aq.)\rightarrow AlCl_3(s)    \Delta H_3=+323kJ     ( ×  2)

(4) 2Al(s)+6HCl(aq.)\rightarrow 2AlCl_3(aq.)+3H_2(g)    \Delta H_4=-1049kJ

The expression for enthalpy of formation of AlCl_3 is,

\Delta H^o_{formation}=[6\times \Delta H_1]+[3\times \Delta H_2]+[2\times \Delta H_3]+[1\times \Delta H_4]

Putting values in above equation, we get:

\Delta H^o_{formation}=[(-74.8\times 6)+(-185\times 3)+(323\times 2)+(-1049\times 1)]=-1406.8kJ

Hence, the \Deltas H^o_{formation} for the reaction is -1406.8 kJ.

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