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GarryVolchara [31]
3 years ago
7

Concentrated hydrogen peroxide solutions are explosively decomposed by traces of transition metal ions (such as Mn or Fe): 2H2O2

(aq) ---> 2H2O(l) + O2(g)
What volume of pure O2(g), collected at 27C and 746 torr, would be generated by decomposition of 125 g of a 50.0% by mass hydrogen peroxide solution?
Chemistry
1 answer:
zalisa [80]3 years ago
8 0

Answer:

23.0733 L

Explanation:

The mass of hydrogen peroxide present in 125 g of 50% of hydrogen peroxide solution:

Mass=\frac {50}{100}\times 125\ g

Mass = 62.5 g

Molar mass of H_2O_2 = 34 g/mol

The formula for the calculation of moles is shown below:

moles = \frac{Mass\ taken}{Molar\ mass}

Thus, moles are:

moles= \frac{62.5\ g}{34\ g/mol}

moles= 1.8382\ mol

Consider the given reaction as:

2H_2O_2_{(aq)}\rightarrow2H_2O_{(l)}+O_2_{(g)}

2 moles of hydrogen peroxide decomposes to give 1 mole of oxygen gas.

Also,

1 mole of hydrogen peroxide decomposes to give 1/2 mole of oxygen gas.

So,

1.8382 moles of hydrogen peroxide decomposes to give \frac {1}{2}\times 1.8382 mole of oxygen gas. Moles of oxygen gas produced = 0.9191 molGiven: Pressure = 746 torr
The conversion of P(torr) to P(atm) is shown below:
[tex]P(torr)=\frac {1}{760}\times P(atm)

So,

Pressure = 746 / 760 atm = 0.9816 atm

Temperature = 27 °C

The conversion of T( °C) to T(K) is shown below:

T(K) = T( °C) + 273.15  

So,  

T₁ = (27 + 273.15) K = 300.15 K

Using ideal gas equation as:

PV=nRT

where,  

P is the pressure

V is the volume

n is the number of moles

T is the temperature  

R is Gas constant having value = 0.0821 L.atm/K.mol

Applying the equation as:

0.9816 atm × V = 0.9191 mol × 0.0821 L.atm/K.mol × 300.15 K

<u>⇒V = 23.0733 L</u>

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Answer:

The higher the temperature, the more soluble most ionic solids are in water

As you cool a saturated solution from high temperature to low temperature, solids start to crystallize out of solution if you achieve a supersaturated solution.

If you raise the temperature of a saturated solution, you can (usually) add more solute and make the solution even more concentrated.

Explanation:

For many ionic solids, solubility in water increases with increase in the temperature of the solution.

This implies that increasing the temperature allow more solute to dissolve in the solvent, supersaturation may be achieved by so doing. As the solution is cooled, the solid crystalizes out of solution hence the answers above.

8 0
3 years ago
Can you pls tell me the net ironic equation of H₂²⁺(aq) + O₂²⁻(aq) + Mg²⁺(aq) + SO₃²⁻(aq) → Mg²⁺(aq)+SO²⁻₄(aq) + H₂O(l)
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Answer:

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H₂²⁺(aq) + O₂²⁻(aq) + SO₃²⁻(aq) → SO²⁻₄(aq) + H₂O(l)

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