The activation energy Ea can be related to rate constant (k) at temperature (T) through the equation:
ln(k2/k1) = Ea/R[1/T1 - 1/T2]
where :
k1 is the rate constant at temperature T1
k2 is the rate constant at temperature T2
R = gas constant = 8.314 J/K-mol
Given data:
k1 = 0.543 s-1; T1 = 25 C = 25+273 = 298 K
k2 = 6.47 s-1; T = 47 C = 47+273 = 320 K
ln(6.47/0.543) = Ea/8.314 [1/298 - 1/320]
2.478 = 2.774 *10^-5 Ea
Ea = 0.8934*10^5 J = 89.3 kJ
Answer:
The correct answer is - option D. the boiling point of solution A will be lower than the boiling point of solution B
Explanation:
Colligative properties such as a decrease in the freezing point of the solution, increase in the boiling point of substance, decrease in Lowering of vapor pressure, and other properties depend upon the number of molecules only.
In the given solution the equal amount of two solutions are mixed that is 50 grams however due to the difference in the molecular mass so the atoms present in both solution A and B will be different. It is known that the number of atoms of a substance is inversely proportional to the molecular mass of the particular substance.
As it is given that Solution B has a low molecular mass which means it has a high number of atoms that means its boiling point will be higher than solution A.
kilo 103 is the correct answer so it would mostly be 2
<span>0.310 moles
First, look up the atomic weights of the elements involved.
Atomic weight carbon = 12.0107
Atomic weight hydrogen = 1.00794
Atomic weight sulfur = 32.065
Molar mass (C3H5)2S = 6 * 12.0107 + 10 * 1.00794 + 32.065
= 114.2086 g/mol
Moles (C3H5)2S = 35.4 g / 114.2086 g/mol = 0.309959145 mol
Since there's just one sulfur atom per (C3H5)2S molecule, the number of moles of sulfur will match the number of moles of (C3H5)2S which is 0.310 when rounded to 3 significant digits.</span>
