The first question's answer is
Answer:
p-fluoronitrobenzene and sodium phenoxide is more appropriate
Explanation:
An ipso substitution is required to form p-nitrophenyl phenyl ether.
For this ipso substitution, an alkoxide anion needs to attack as a nucleophile at the carbon atom attached to fluorine atom and thereby substitute that F atom.
p-nitrophenoxide is an weak nucleophile as compared to phenoxide due to presence of electron withdrawing resonating effect of nitro group at para position.
p-fluoronitrobenzene is a good choice for nucleophilic attack by alkoxide anion as compared to fluorobenzene due to higher positive charge density at carbon atom directly attached to F atom. Higher positive charge density arises due to presence of electron withdrawing resonating effect og nitro group at para position.
So, p-fluoronitrobenzene and sodium phenoxide is more appropriate
Answer : The molecular weight of a substance is 157.3 g/mol
Explanation :
As we are given that 7 % by weight that means 7 grams of solute present in 100 grams of solution.
Mass of solute = 7 g
Mass of solution = 100 g
Mass of solvent = 100 - 7 = 93 g
Formula used :

where,
= change in freezing point
= temperature of pure water = 
= temperature of solution = 
= freezing point constant of water = 
m = molality
Now put all the given values in this formula, we get


Therefore, the molecular weight of a substance is 157.3 g/mol
The balanced chemical reaction:
C3H8 + 5O2 = 3CO2 + 4H2O
We are given the amount of the carbon dioxide to be produced. This will be the starting point of our calculations.
<span>43.62 L CO2 ( 1 mol CO2 / 22.4 L CO2 ) (5 mol O2 / 3 mol CO2 ) (
22.4 L O2 / 1 mol O2) = 72.7 L O2</span>