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This problem is simply converting the concentration from molality to molarity. Molality has units of mol solute/kg solvent, while molarity has units of mol solute/L solution.
2.24 mol H2SO4/kg H2O * (0.25806 kg H2SO4/mol H2SO4) = 0.578 kg H2SO4/kg H2O
That means the solution weighs a total of 1 kg + 0.578 kg = 1.578 kg. Then, convert it to liters using the density data:
1.578 kg * (1000g / 1kg) * (1 mL/1.135 g) = 1390 mL or 1.39 L.
Hence, the molarity is
2.24/1.39 = 1.61 M
and
.
Assuming complete decomposition of both samples,
First compound:
;
of the first compound would contain
Oxygen and mercury atoms seemingly exist in the first compound at a
ratio; thus the empirical formula for this compound would be
where the subscript "1" is omitted.
Similarly, for the second compound
;
of the first compound would contain
and therefore the empirical formula
.