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mixer [17]
2 years ago
8

The solubility of acetanilide is 12.8 g in 100 mL of ethanol at 0 ∘C, and 46.4 g in 100 mL of ethanol at 60 ∘C. What is the maxi

mum percent recovery that can be achieved for the recrystallization of acetanilide from ethanol?
A student was given a sample of crude acetanilide to recrystallize. The initial mass of the the crude acetanilide was 171 mg.The mass after recrystallization was 125 mg.

Calculate the percent recovery from recrystallization.
Chemistry
1 answer:
weqwewe [10]2 years ago
3 0

Answer: 72.41% and 26.90% respectively.

Explanation:

At 60°C, you can dissolve 46.4g of acetanilide in 100mL of ethanol. If you lower the temperature, at 0°C, you can dissolve just 12.8g, which means (46.4g-12.8g)=33.6g of acetanilide must have precipitated from the solution.

We can calculate recovery as:

\%R=\frac{crystalized\ mass}{initial\ mass}*100 =\frac{33.6\ g}{46.4\ g}*100=72.41\%

So the answer to the first question is 72.41%.

For the second part just use the same formula, the mass of the precipitate is the final mass minus the initial mass, (171mg-125mg)=46mg.

\%R=\frac{crystalized\ mass}{initial\ mass}*100 =\frac{46\ mg}{171\ mg}*100=26.90\%

So the answer to the second question is 26.90%.

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In this reaction, a gaseous system with a volume of 3.00 L has a rate of formation of NOCl of 0.0120 M s-1 . The volume of the s
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Answer:

x = 0.324 M s⁻¹

Explanation:

Equation for the reaction can be represented as:

 2 NO(g)   + Cl₂ (g)      ⇄     2NOCl (g)

Rate = K [NO]² [Cl₂]

Concentration = \frac{numbers of mole (n)}{volume (v)}

from the question; their number of moles are constant since the species are quite alike.

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we have: Concentration ∝ \frac{1}{v}

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Rate = K [NO]² [Cl₂]

Rate = (\frac{1}{v}) ^2 (\frac{1}{v} )

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We were also told that the in the reaction, the gaseous system has an initial volume of 3.00 L and rate of formation of 0.0120 Ms⁻¹

So we can have:

0.0120 = \frac{1}{3^3}

0.0120 = \frac{1}{27}   -----Equation (1)

Now; the new rate of formation when the  volume of the system decreased to 1.00 L can now be calculated as:

x = (\frac{1}{1})^3

x = 1             ------- Equation (2)

Dividing equation (2) with equation (1); we have:

\frac{0.0210}{x} = \frac{\frac{1}{27} }{1}

\frac{0.0210}{x} = \frac{1}{27}

x = 0.0120 × 27

x = 0.324 M s⁻¹

∴  the new rate of formation of NOCl = 0.324 M s⁻¹

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