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defon
3 years ago
6

Determine the limiting reactant (lr) and the mass (in g) of nitrogen that can be formed from 50.0 g n2o4 and 45.0 g n2h4. some p

ossibly useful molar masses are as follows: n2o4 = 92.02 g/mol, n2h4 = 32.05 g/mol. n2o4(l) + 2 n2h4(l) → 3 n2(g) + 4 h2o(g) determine the limiting reactant (lr) and the mass (in g) of nitrogen that can be formed from 50.0 g n2o4 and 45.0 g n2h4. some possibly useful molar masses are as follows: n2o4 = 92.02 g/mol, n2h4 = 32.05 g/mol. n2o4(l) + 2 n2h4(l) → 3 n2(g) + 4 h2o(g) lr = n2o4, 105 g n2 formed lr = n2h4, 59.0 g n2 formed lr = n2o4, 45.7 g n2 formed no lr, 45.0 g n2 formed lr = n2h4, 13.3 g n2 formed
Chemistry
1 answer:
Licemer1 [7]3 years ago
4 0
                                                   N2O4(l) + 2 N2H4(l) → 3 N2(g) + 4 H2O(g)
1) to calculate the limiting reactant you need to pass grams to moles.
<span> moles is calculated by dividing mass by molar mass
</span>
mass of N2O4: 50.0 g 
molar mass of <span>N2O4 = 92.02 g/mol
</span><span>molar mass of N2H4 = 32.05 g/mol.
</span>mass of N2H4:45.0 g

moles N2O4=50.0/92.02 g/mol= 0,54 mol of N2O4
moles N2H4= 45/32.05 g/mol= 1,40 mol of <span><span>N2H4

</span> 2)</span>
By looking at the balanced equation, you can see that 1 mol of N2O4 needs 2 moles of N2H4 to fully react . So to react  0,54 moles of N2O4, you need 2x0,54 moles of <span>N2H4 moles
</span><span>N2H4 needed = 1,08 moles.
You have more that 1,08 moles </span><span>N2H4, so this means the limiting reagent is not N2H4, it's </span>N2O4. The molecule that has molecules that are left is never the limiting reactant.

3) 1 mol of N2O4 reacting, will produce 3 mol of N2 (look at the equation)
There are 0,54 mol of N2O4 available to react, so how many moles will produce of N2?
1 mol N2O4------------3 mol of N2
0,54 mol N2O4--------x
x=1,62 mol of N2

4) the only thing left to do is convert the moles obtained, to grams.
We use the same formula as before, moles equal to mass divided by molar mass.
moles= \frac{grams}{molar mass}             (molar mass of N2= 28)
1,62 mol of N2= mass/ 28
mass of N2= 45,36 grams

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3 years ago
Question 1(Multiple Choice Worth 4 points)
zubka84 [21]

<u>Answer </u>

Answer 1 : 28.9 g of CO is needed.

Answer 2 : Six moles of H_{2}O over Nine moles of O_{2}

Answer 3 : Four over two fraction can be used for the mole ratio to determine the mass of Fe from a known mass of Fe_{2}O_{3}.

Answer 4 : Mass of O_{2} = (150 × 3 × 31.998) ÷ (232.29 × 1) grams

Answer 5 : 8.4 moles of sodium cyanide (NaCN) would be needed.

<u>Solution </u>

Solution 1 : Given,

Given mass of Fe_{2}O_{3} = 55 g

Molar mass of Fe_{2}O_{3} = 159.69 g/mole

Molar mass of CO = 28.01 g/mole

Moles of Fe_{2}O_{3} = \frac{\text{ Given mass of } Fe_{2}O_{3}}{\text{ Molar mass of } Fe_{2}O_{3}} = \frac{55 g}{159.69 g/mole} = 0.344 moles

Balanced chemical reaction is,

Fe_{2}O_{3}(s)+3CO(g)\rightarrow 2Fe(s)+3CO_{2}(g)

From the given reaction, we conclude that

1 mole of Fe_{2}O_{3} gives              →         3 moles of CO

0.344 moles of Fe_{2}O_{3} gives    →         3 × 0.344 moles of CO

                                                     =         1.032 moles

Mass of CO = Number of moles of CO × Molar mass of CO

                    = 1.032 × 28.01

                    = 28.90 g

Solution 2 : The balanced chemical reaction is,

2C_{3}H_{6}+9O_{2}\rightarrow 6CO_{2}+6H_{2}O

From the given reaction, we conclude that the Six moles of H_{2}O over Nine moles of O_{2} is the correct option.

Solution 3 : The balanced chemical reaction is,

4Fe+3O_{2}\rightarrow 2Fe_{2}O_{3}

From the given balanced reaction, we conclude that Four over two fraction can be used for the mole ratio to determine the mass of Fe from a known mass of Fe_{2}O_{3}.

Solution 4 : Given,

Given mass of Zn(ClO_{3})_{2} = 150 g

Molar mass of Zn(ClO_{3})_{2} = 232.29 g/mole

Molar mass of O_{2} = 31.998 g/mole

Moles of Zn(ClO_{3})_{2} = \frac{\text{ Given mass of }Zn(ClO_{3})_{2} }{\text{ Molar mass of } Zn(ClO_{3})_{2}} = (\frac{150\times 1}{232.29})moles

The balanced chemical equation is,

Zn(ClO_{3})_{2}}\rightarrow ZnCl_{2}+3O_{2}

From the given balanced equation, we conclude that

1 mole of Zn(ClO_{3})_{2} gives          →       3 moles of O_{2}

(\frac{150\times 1}{232.29})moles of Zn(ClO_{3})_{2} gives  →  [(\frac{150\times 1}{232.29})\times 3] moles of O_{2}

Mass of O_{2} = Number of moles of O_{2} × Molar mass of  O_{2} = [(\frac{150\times 1}{232.29})\times 3] \times 31.998 grams

Therefore, the mass of O_{2} = (150 × 3 × 31.998) ÷ (232.29 × 1) grams

Solution 5 : Given,

Number of moles of Na_{2}SO_{4} = 4.2 moles

Balanced chemical equation is,

H_{2}SO_{4}+2NaCN\rightarrow 2HCN+Na_{2}SO_{4}

From the given chemical reaction, we conclude that

1 mole of Na_{2}SO_{4} obtained from 2 moles of NaCN

4.2 moles of Na_{2}SO_{4} obtained   →   2 × 4.2 moles of NaCN

Therefore,

The moles of NaCN needed = 2 × 4.2 = 8.4 moles


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How do you solve stoichiometry problems
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Ok so the way I do it is as simple as possible.
Firstly look at the reactants and products ( there can be one reactant and one product or more ) you will usually be given the moles of the reactant or products, if you are given grams you can convert into moles by this convertion ( grams/R.M.M ) where R.M.M is the relative atomic mass of your substance ( the mass number of all of the elements in your substance).

Ok when you have moles now look at the ratio between the products and reactants. Usually you will won't know the moles of one substance therefore you will be asked to find moles or mass of that substance.

For example:

When 16 grams of oxygen and 1 gram of hydrogen gas react to produce water. Find the number of grams of water being produced.

O2 + 2H2 -> 2H2O
16g      2g          xg

Here we're told the mass of the reactants. In stoichiometry we need to work with moles therefore you need to calculate moles of the reactants.
Firstly find the R.M.M of each reactant.
R.M.M of O2 is 16+16=32 since it's diatomic we add atomic masses of two oxygen atoms.
R.M.M of H2 is 1+1=2, it's also diatomic. (Diatomic two atoms of the same element are joined together). (Ignore the number 2 in front of H2, this number shows us the ratio relationship between reactans or products, i.e when we balance an equation.)

Ok so now find moles:

We have 16 grams of O2
16/R.M.M
16/32 = 0.5 moles

We have 2 grams of H2
1/R.M.M
2/2 = 1 mole
Now back to the equation.

O2 + 2H2 -> 2H2O
0.5 moles 1mole xmoles                  (it's xmoles because we don't know                                                               molarity of water that's what we have                                                           find firstly in order to find grams.)
Now look at the ratio between any reactant and product i.e you can choose which reactant to compare to the product, it doesn't make a different ( I will do two or you can do two at the same time)

1st method:
Look at the ratio between O2 and H2O from the reaction above we see the ratio is 1:2 therefore for every 0.5 moles of O2 you get 1 mole of H2O.
1:2
0.5 : x
0.5*2 = 1

2nd method;
Look at the ratio betweem H2 and H2O from the reaction above we see the ratio is 2:2 or 1:1. We have 1 mole of H2 there we must have 1 mole of H2O. We see this is true as both methods give us 1 mole of H2O.

3rd method ( combined):
Look at the ratio between O2, H2 and H2O.
We see that the ratio is 1:2:2
So we have 0.5:1:x
If we multiply 0.5 *2 it equals 1 mole
If we multiply 1*1 we get 1 moles.
Any method is correct and it's up to you to find a comfortable way.
We're not finished in the question we are asked for the mass of water.
So just multiply the number of moles (1mole) by R.M.M of H2O.
1 * R.M.M
R.M.M of H2O = 1+1+16=18
1*18= 18 grams.
And you're finished.

I am sorry if this is so long I want you to understand as much as possible.
In stoichiometry you can also be asked about the empirical formula of a substance. I can show you how do it. If you have any question just tell me.
Hope this helps :).
7 0
3 years ago
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