Answer:
0.3023 M
Explanation:
Let Picric acid = 
So,
+
⇄
+ 
The ICE table can be given as:
+
⇄
+ 
Initial: 0.52 0 0
Change: - x + x + x
Equilibrium: 0.52 - x + x + x
Given that;
acid dissociation constant (
) = 0.42
![K_a = \frac{[H_3O^+][Picric^-]}{H_{picric}}](https://tex.z-dn.net/?f=K_a%20%3D%20%5Cfrac%7B%5BH_3O%5E%2B%5D%5BPicric%5E-%5D%7D%7BH_%7Bpicric%7D%7D)
![0.42 = \frac{[x][x]}{0.52-x}}](https://tex.z-dn.net/?f=0.42%20%3D%20%5Cfrac%7B%5Bx%5D%5Bx%5D%7D%7B0.52-x%7D%7D)
![0.42 = \frac{[x]^2}{0.52-x}}](https://tex.z-dn.net/?f=0.42%20%3D%20%5Cfrac%7B%5Bx%5D%5E2%7D%7B0.52-x%7D%7D)
0.42(0.52-x) = x²
0.2184 - 0.42x = x²
x² + 0.42x - 0.2184 = 0 -------------------- (quadratic equation)
Using the quadratic formula;
; ( where +/- represent ± )
= 
= 
=
OR 
=
OR 
=
OR 
= 0.30225 OR - 0.72225
So, we go by the +ve integer that says:
x = 0.30225
x = [
] = [
] = 0.3023 M
∴ the value of [H3O+] for an 0.52 M solution of picric acid = 0.3023 M (to 4 decimal places).
I think the correct answer is the first option. It has nonpolar bonds and a symmetrical structure. The structure of a BF3 molecule shows a symmetrical trigonal geometry. The net dipole moment of the molecule is zero therefore it is polar.
Balanced there are 2 Al, 6 oxygens on both sides.