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Sladkaya [172]
3 years ago
9

For each of the following substituents, indicate whether it withdraws electrons inductively, donates electrons by hyperconjugati

on, withdraws electrons by resonance, or donates electrons by resonance. (Effects should be compared with that of a hydrogen; remember that many substituents can be characterized in more than one way.)
a. Br
b. CH2CH3
c. NHCH3
d. OCH3
Chemistry
1 answer:
AveGali [126]3 years ago
3 0

Answer:

a. withdraws electrons inductively

b. donates electrons by hyperconjugation

c. donates electrons by resonance

d.  withdraws electrons inductively

Explanation:

a.  The bromide ion is a highly electronegative ion (in the halide series). Electronegative substituents on acids increase the acidity by inductive electron withdrawal method. The higher the electronegativity of a substance, the greater the acidity. The halogens have this order of electronegativity:

F > Cl > Br>I

b.  The carboxyl groups have a stabilization of the sigma and pi bonds. This is achieved through a special delocalization of electrons.  Because of the delocalization, hyperconjugation is the result effect.

c. The NHCH₃ group has a highly electonegative nitrogen atom that pulls the electron cloud towards itself. In this case, it withdraws electrons inductively. As a result, it donates electrons by resonance.

d. The OCH₃ group has a highly electonegative oxygen atom. This oxygen atom withdraws electron cloud towards itself. As a result, it withdraws electrons inductively.

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NikAS [45]

The question is incomplete, here is the complete question:

Classify each element. Note that another term for main group is representative, another term for semi-metal is metalloid, and the inner transition metals are also called the lanthanide and actinide series.

Hf, Am, In, Ta, As, Se, Rn

<u>Answer:</u>

Hafnium and tantalum are transition elements.

Americium is a inner transition element.

Indium, Selenium and Radon are main group elements.

Arsenic is a metalloid.

<u>Explanation:</u>

Main group elements are the elements which belong to s block and p block. They are also known as representative elements.

S-block elements are defined as the elements whose last electron enters s-sub shell. The general electronic configuration of these elements is ns^{1-2}

P-block elements are defined as the elements whose last electron enters p-sub shell. The general electronic configuration of these elements is np^{1-6}

Metalloids are defined as the elements which show intermediate properties between metals and non-metals. There are 7 metalloids in the periodic table. They are: Boron, Silicon, germanium, Arsenic, Antimony, Tellurium and Polonium.

Transition elements are known as d-block elements. D block elements are defined as the elements whose last electron enters d sub shell. The general electronic configuration of these elements is [(n-1)d^{1-10}ns^{0-2}]

Inner transition elements are known as (f block) elements. (F block) elements are defined as the elements whose last electron enters (f subshell). The general electronic configuration of these elements is [(n-2)f^{1-14}(n-1)d^{0-1}ns^{2}]. They are also known as lanthanide and actinide series.

For the given elements:

  • <u>Option 1:</u> Hf

Hafnium is the 72nd element of the periodic table having electronic configuration of [Xe]4f^{14}5d^26s^2

As, the last electron is entering the d subshell, it is a transition element.

  • <u>Option 2:</u> Am

Americium is the 95th element of the periodic table having electronic configuration of [Rn]5f^{7}6d^07s^2

As, the last electron is entering the (f subshell), it is a inner transition element.

  • <u>Option 3:</u> In

Indium is the 49th element of the periodic table having electronic configuration of [Kr]5s^25p^1

As, the last electron is entering the p subshell, it is a main group element.

  • <u>Option 4:</u> Ta

Tantalum is the 73rd element of the periodic table having electronic configuration of [Xe]4f^{14}5d^56s^2

As, the last electron is entering the d subshell, it is a transition element.

  • <u>Option 5:</u> As

Arsenic is the 33rd element of the periodic table having electronic configuration of [Ar]4s^24p^3

As, the last electron is entering the p subshell, it is a main group element. It shows an intermediate property of metal and non-metal. Thus, it is a metalloid.

  • <u>Option 6:</u> Se

Selenium is the 34th element of the periodic table having electronic configuration of [Ar]4s^24p^4

As, the last electron is entering the p subshell, it is a main group element.

  • <u>Option 7:</u> Rn

Radon is the 86th element of the periodic table having electronic configuration of [Xe]4f^{14}5d^{10}6s^26p^6

As, the last electron is entering the p subshell, it is a main group element.

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1) if we have 1 kg of water which is same as 1000 grams of water. 

2) we need to convert grams to moles using the molar mass of water 

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