Pcl5 exist but ncl5 does not.why?
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The question is partially incorrect, because nitration of <span> methyl benzoate results in generation of methyl 3-nitrobenzoate, and not methyl 2-benzoate.
This a because of the present of ester group, which deactivated benzene ring at ortho and para position. Due to this, the electrophile (NO2+) attackes on meta position.
The detailed mechanism is attached below.</span>
This a because of the present of ester group, which deactivated benzene ring at ortho and para position. Due to this, the electrophile (NO2+) attackes on meta position.
The detailed mechanism is attached below.</span>