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sveta [45]
3 years ago
12

The density of the fat tristearin is 0.95 g cm−3 . Calculate the change in molar Gibbs energy of tristearin when a deep-sea crea

ture is brought to the surface (p = 1.0 atm) from a depth of 2.0 km. To calculate the hydrostatic pressure, take the mean density of water to be 1.03 g cm−3 .
Chemistry
1 answer:
KatRina [158]3 years ago
8 0

The formula for the change in Gibbs energy of a solid is:

ΔG = Vm ΔP

where, ΔG is change in Gibbs, Vm is molar volume, ΔP is change in pressure

ΔP = P(final) – P(initial)

P(final) = 1 atm = 101325 Pa

P(initial) = ρ_water *g *h = (1030 kg/m^3) * 9.8 m/s^2 * 2000 m = 20188000 kg m/s^2 = 20188000 Pa

Vm = (950 kg/m^3) * (1000 mol / 891.48 kg) = 1065.64 mol/m^3

 

So,

ΔG = (1065.64 mol/m^3) * (101325 Pa - 20188000 Pa)

<span>ΔG = -21405164347 J = -21.4 GJ</span>

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Calculate the pH for each of the following cases in the titration of 50.0 mL of 0.210 M HClO(aq) with 0.210 M KOH(aq).
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a) before addition of any KOH : 

when we use the Ka equation & Ka = 4 x 10^-8 : 

Ka = [H+]^2 / [ HCIO]

by substitution:

4 x 10^-8 = [H+]^2 / 0.21

[H+]^2 = (4 x 10^-8) * 0.21

           = 8.4 x 10^-9

[H+] = √(8.4 x 10^-9)

       = 9.2 x 10^-5 M

when PH = -㏒[H+]

   PH = -㏒(9.2 x 10^-5)

        = 4  

b)After addition of 25 mL of KOH: this produces a buffer solution 

So, we will use Henderson-Hasselbalch equation to get PH:

PH = Pka +㏒[Salt]/[acid]


first, we have to get moles of HCIO= molarity * volume

                                                           =0.21M * 0.05L

                                                           = 0.0105 moles

then, moles of KOH = molarity * volume 

                                  = 0.21 * 0.025

                                  =0.00525 moles 

∴moles HCIO remaining = 0.0105 - 0.00525 = 0.00525

and when the total volume is = 0.05 L + 0.025 L =  0.075 L

So the molarity of HCIO = moles HCIO remaining / total volume

                                        = 0.00525 / 0.075

                                        =0.07 M

and molarity of KCIO = moles KCIO / total volume

                                    = 0.00525 / 0.075

                                    = 0.07 M

and when Ka = 4 x 10^-8 

∴Pka =-㏒Ka

         = -㏒(4 x 10^-8)

         = 7.4 

by substitution in H-H equation:

PH = 7.4 + ㏒(0.07/0.07)

∴PH = 7.4 

c) after addition of 35 mL of KOH:

we will use the H-H equation again as we have a buffer solution:

PH = Pka + ㏒[salt/acid]

first, we have to get moles HCIO = molarity * volume 

                                                        = 0.21 M * 0.05L

                                                        = 0.0105 moles

then moles KOH = molarity * volume
                            =  0.22 M* 0.035 L 

                            =0.0077 moles 

∴ moles of HCIO remaining = 0.0105 - 0.0077=  8 x 10^-5

when the total volume = 0.05L + 0.035L = 0.085 L

∴ the molarity of HCIO = moles HCIO remaining / total volume 

                                      = 8 x 10^-5 / 0.085

                                      = 9.4 x 10^-4 M

and the molarity of KCIO = moles KCIO / total volume

                                          = 0.0077M / 0.085L

                                          = 0.09 M

by substitution:

PH = 7.4 + ㏒( 0.09 /9.4 x 10^-4)

∴PH = 8.38

D)After addition of 50 mL:

from the above solutions, we can see that 0.0105 mol HCIO reacting with 0.0105 mol KOH to produce 0.0105 mol KCIO which dissolve in 0.1 L (0.5L+0.5L) of the solution.

the molarity of KCIO = moles KCIO / total volume

                                   = 0.0105mol / 0.1 L

                                   = 0.105 M

when Ka = KW / Kb

∴Kb = 1 x 10^-14 / 4 x 10^-8

       = 2.5 x 10^-7

by using Kb expression:

Kb = [CIO-] [OH-] / [KCIO]

when [CIO-] =[OH-] so we can substitute by [OH-] instead of [CIO-]

Kb = [OH-]^2 / [KCIO] 

2.5 x 10^-7 = [OH-]^2 /0.105

∴[OH-] = 0.00016 M

POH = -㏒[OH-]

∴POH = -㏒0.00016

           = 3.8
∴PH = 14- POH

        =14 - 3.8

PH = 10.2

e) after addition 60 mL of KOH:

when KOH neutralized all the HCIO so, to get the molarity of KOH solution

M1*V1= M2*V2

 when M1 is the molarity of KOH solution

V1 is the total volume = 0.05 + 0.06 = 0.11 L

M2 = 0.21 M 

V2 is the excess volume added  of KOH = 0.01L

so by substitution:

M1 * 0.11L = 0.21*0.01L

∴M1 =0.02 M

∴[KOH] = [OH-] = 0.02 M

∴POH = -㏒[OH-]

           = -㏒0.02 

           = 1.7

∴PH = 14- POH

       = 14- 1.7 

      = 12.3 
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What occurs when kcl(s is added to water?
Mama L [17]
When KCL, which is an ionic compound is added to water it will dissociate and or ionize completely forming the ions of K+ and Cl-. The resulting solution would be a neutral solution, as the K+ is a cation of a strong base and Cl- is an anion of a strong acid, and whenever a strong base reacts with a strong acid, a neutral salt is produced
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Hydroxyapatite, Ca 10 ( PO 4 ) 6 ( OH ) 2 , has a solubility constant of Ksp = 2.34 × 10 − 59 , and dissociates according to Ca
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Answer: 4M

Explanation:

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Need help asap with this chemistry if someone could help me
Burka [1]

Answer:

<h3>1)</h3>

Structure One:

  • N: -2
  • C: 0
  • O: +1

Structure Two:

  • N: 0
  • C: 0
  • O: -1

Structure Three:

  • N: -1
  • C: 0
  • O: 0.

Structure Number Two would likely be the most stable structure.

<h3>2)</h3>
  • All five C atoms: 0
  • All six H atoms to C: 0
  • N atom: +1.

The N atom is the one that is "likely" to be attracted to an anion. See explanation.

Explanation:

When calculating the formal charge for an atom, the assumption is that electrons in a chemical bond are shared equally between the two bonding atoms. The formula for the formal charge of an atom can be written as:

\text{Formal Charge} \\ = \text{Number of Valence Electrons in Element} \\ \phantom{=}-\text{Number of Chemical Bonds} \\\phantom{=} - \text{Number of nonbonding Lone Pair Electrons}.

For example, for the N atom in structure one of the first question,

  • N is in IUPAC group 15. There are 15 - 10 = 5 valence electrons on N.
  • This N atom is connected to only 1 chemical bond.
  • There are three pairs, or 6 electrons that aren't in a chemical bond.

The formal charge of this N atom will be 5 - 1 - 6 = -2.

Apply this rule to the other atoms. Note that a double bond counts as two bonds while a triple bond counts as three.

<h3>1)</h3>

Structure One:

  • N: -2
  • C: 0
  • O: +1

Structure Two:

  • N: 0
  • C: 0
  • O: -1

Structure Three:

  • N: -1
  • C: 0
  • O: 0.

In general, the formal charge on all atoms in a molecule or an ion shall be as close to zero as possible. That rules out Structure number one.

Additionally, if there is a negative charge on one of the atoms, that atom shall preferably be the most electronegative one in the entire molecule. O is more electronegative than N. Structure two will likely be favored over structure three.

<h3>2)</h3>

Similarly,

  • All five C atoms: 0
  • All six H atoms to C: 0
  • N atom: +1.

Assuming that electrons in a chemical bond are shared equally (which is likely not the case,) the nitrogen atom in this molecule will carry a positive charge. By that assumption, it would attract an anion.

Note that in reality this assumption seldom holds. In this ion, the N-H bond is highly polarized such that the partial positive charge is mostly located on the H atom bonded to the N atom. This example shows how the formal charge assumption might give misleading information. However, for the sake of this particular problem, the N atom is the one that is "likely" to be attracted to an anion.

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