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Yakvenalex [24]
3 years ago
13

Consider the reaction when aqueous solutions of potassium hydroxide and ammonium nitrate are combined. The net ionic equation fo

r this reaction is:
Chemistry
1 answer:
Reil [10]3 years ago
6 0

Answer: OH^-(aq)+NH_4^+(aq)\rightarrow NH_3(g)+H_2O(l)

Explanation:

A double displacement reaction is one in which exchange of ions take place. The salts which are soluble in water are designated by symbol (aq) and those which are insoluble in water and remain in solid form are represented by (s) after their chemical formulas.

KOH(aq)+NH_4NO_3(aq)\rightarrow KNO_3(aq)+NH_3(g)+H_2O(l)

The equation can be written in terms of ions as:

K^+(aq)+OH^-(aq)+NH_4^+(aq)+NO_3^-(aq)\rightarrow K^+(aq)+NO_3^-(aq)+NH_3(g)+H_2O(l)

Spectator ions are defined as the ions which does not get involved in a chemical equation or they are ions which are found on both the sides of the chemical reaction present in ionic form.

The ions which are present on both the sides of the equation are potassium and nitrate ions and hence are not involved in net ionic equation.

Hence, the net ionic equation is :

OH^-(aq)+NH_4^+(aq)\rightarrow NH_3(g)+H_2O(l)

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Use the data given below to construct a Born-Haber cycle to determine the second ionization energy of Ca. Δ H°(kJ) Ca(s)→Ca(g) 1
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Answer :  The value of second ionization energy of Ca is 1010 kJ.

Explanation :  

The formation of calcium oxide is,

Ca(s)+\frac{1}{2}O_2(g)\overset{\Delta H_f}\rightarrow CaO(s)

\Delta H_f^o = enthalpy of formation of calcium oxide = -635 kJ

The steps involved in the born-Haber cycle for the formation of CaO:

(1) Conversion of solid calcium into gaseous calcium atoms.

Ca(s)\overset{\Delta H_s}\rightarrow Ca(g)

\Delta H_s = sublimation energy of calcium = 193 kJ

(2) Conversion of gaseous calcium atoms into gaseous calcium ions.

Ca(g)\overset{\Delta H_I_1}\rightarrow Ca^{+1}(g)

\Delta H_I_1 = first ionization energy of calcium = 590 kJ

(3) Conversion of gaseous calcium ion into gaseous calcium ions.

Ca^{+1}(g)\overset{\Delta H_I_2}\rightarrow Ca^{+2}(g)

\Delta H_I_2 = second ionization energy of calcium = ?

(4) Conversion of molecular gaseous oxygen into gaseous oxygen atoms.

O_2(g)\overset{\Delta H_D}\rightarrow OI(g)

\frac{1}{2}O_2(g)\overset{\Delta H_D}\rightarrow O(g)

\Delta H_D = dissociation energy of oxygen = \frac{498}{2}=249kJ

(5) Conversion of gaseous oxygen atoms into gaseous oxygen ions.

O(g)\overset{\Delta H_E_1}\rightarrow O^-(g)

\Delta H_E_1 = first electron affinity energy of oxygen = -141 kJ

(6) Conversion of gaseous oxygen ion into gaseous oxygen ions.

O^-(g)\overset{\Delta H_E_2}\rightarrow O^{2-}(g)

\Delta H_E_2 = second electron affinity energy of oxygen = 878 kJ

(7) Conversion of gaseous cations and gaseous anion into solid calcium oxide.

Ca^{2+}(g)+O^{2-}(g)\overset{\Delta H_L}\rightarrow CaO(s)

\Delta H_L = lattice energy of calcium oxide = -3414 kJ

To calculate the overall energy from the born-Haber cycle, the equation used will be:

\Delta H_f^o=\Delta H_s+\Delta H_I_1+\Delta H_I_2+\Delta H_D+\Delta H_E_1+\Delta H_E_2+\Delta H_L

Now put all the given values in this equation, we get:

-635kJ=193kJ+590kJ+\Delta H_I_2+249kJ+(-141kJ)+878kJ+(-3414kJ)

\Delta H_I_2=1010kJ

Therefore, the value of second ionization energy of Ca is 1010 kJ.

6 0
3 years ago
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