The solubility of lead(ii) chloride is 0.45 g/100 ml of solution. what is the ksp of pbcl2? 4.9 × 10-2 1.7 × 10-5 8.5 × 10-6 4.2
1 answer:
You might be interested in
Answer:
1 ) Δs ( entropy change for hot block ) = - Q / th ( -ve shows heat lost to cold block )
Δs ( entropy change for cold block ) = Q / tc
∴ Total Δs = ΔSc + ΔSh
= Q/tc - Q/th
2) ΔSdecomposition = Δh / Temp = ( 181.6 * 10^3 / 773 ) = 234.928 J/k
Explanation:
<u>1) To show that heat flows spontaneously from high temperature to low temperature </u>
example :
Pick two(2) solid metal blocks with varying temperatures ( i.e. one solid block is hot and the other solid block is cold )
Place both blocks for time (t ) in an insulated system to reduce heat loss or gain to or from the environment
Check the temperature of both blocks after time ( t ) it will be observed that both blocks will have same temperature after time t ( first law of thermodynamics )
Δs ( entropy change for hot block ) = - Q / th ( -ve shows heat lost to cold block )
Δs ( entropy change for cold block ) = Q / tc
∴ Total Δs = ΔSc + ΔSh
= Q/tc - Q/th
<u>2) Entropy change for Decomposition of mercuric oxide </u>
2HgO (s) → 2Hg(l) + O₂ (g)
Δs = positive
there is transition from solid to liquid and the melting point of mercury ( the point at which reaction will take place ) = 500⁰C
hence ΔSdecomposition = S⁻ Hg - S⁻ HgO =
Δh of reaction = 181.6 KJ
Temp = 500 + 273 = 773 k
hence ΔSdecomposition = Δh / Temp = ( 181.6 * 10^3 / 773 ) = 234.928 J/k
Answer:
Heat transfer in step 2 = 47.75 J
Explanation:
Internal energy = heat + work done
U = Q + W
In a cyclic process the total internal energy change of the system = 0.
In the process there are two steps. The total heat exchange in the process is the sum of heat exchanges in the two processes.
We have to find the heat exchange in step 2.
In step 1,
W = 1.25 J Q = -37 J
= -37 + 1.25 = -35.75 J
In step 2, the internal energy change will be negative of that in step 1.
U = 35.75 J
W = -12 J
U = Q + W
35.75 = Q -12
Q = 47.75 J
Heat transfer in step 2 = 47.75 J