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Reil [10]
3 years ago
14

At a certain temperature, Kc = 0.0500 and ∆H = +39.0 kJ for the reaction below, 2 MgCl2(s) + O2(g) → 2MgO(s) + Cl2(g) Calculate

Kc for the reaction, MgO(s) + ½ Cl2(g) → MgCl2(s) + ½ O2(g) and indicate whether the value of Kc will be larger or smaller at a lower temperature.
Chemistry
1 answer:
Minchanka [31]3 years ago
6 0

Explanation:

Since, it is shown that the reaction has been reversed. Therefore, value of K_{c} will become \frac{1}{K_{c}}.

Hence, new K_{c'} = \frac{1}{K_{c}}

                                      = \frac{1}{0.0500}

                                      = 20

Also, the number of moles of each reactant has been halved. So, K_{c''} for the reaction MgO(s) + \frac{1}{2}Cl2(g) → MgCl_{2}(s) + \frac{1}{2} O2(g) will also get halved.

Therefore,     K_{c''}  = K_{c'} = (20)^{0.5}

                               = 4.47

As the value of \Delta H is given as +39.0 kJ. So, it means that the reaction is endothermic in nature. So, energy of reactants will be more than the products. Hence, according to Le Chatelier's principle reaction will move in the forward direction.

As a result, K_{c} will also increase with increase in temperature.

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3 years ago
During the process of heat transfer, the heat transferred to or from a system's surroundings is always?
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During the process of heat transfer, the heat transferred to or from a system's surroundings is always equal in magnitude to the heat transferred to or from the system, but opposite in sign.

<h2>What is the 1st law of thermodynamics?</h2>

The total energy of an isolated system is said to stay constant according to the first rule of thermodynamics. Energy cannot be generated or destroyed, but it may be transformed from one form into another inside a closed system, which is known as the conservation of energy.

This rule states that when a system is exposed to a certain amount of heat, the amount of heat that the system absorbs is equal to the product of the increase in internal energy (change in internal energy) of the system and the external work that the system does. The relationship between a system's internal energy and work output and the heat given to it is demonstrated by the first law of thermodynamics. This equation provides the foundation for the majority of practical innovations like heat engines, freezers, and air conditioners.

The equation for the first law of thermodynamics is given as; ΔU = q + W

Where,

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The heat transported to or from a system's surroundings during the process of heat transfer is always opposite in sign, but equal in size, to the heat transferred to or from the system.

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       The flow of thermal energy between physical systems is known as heat transfer. The temperatures of the systems and the characteristics of the medium used to transmit the heat affect how quickly it transfers. Conduction, convection, and radiation are the three basic ways that heat is transferred. It is crucial to employ heat transfer, or the movement of energy in the form of heat, in applications of the First Law of Thermodynamics since it is a mechanism through which a system changes its internal energy. Diffusion and conduction are two different concepts. Diffusion linked to fluid mixing is not the same as conduction.

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The volume of HCl which is required to reach the equivalence point can be calculated in the way given as follows.

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learn more about equivalence point:

brainly.com/question/19997690

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