Answer:
Explanation:
Because 3.005 grams of potassium lactate is added to 100. mL of solution, its concentration is:
![\displaystyle \begin{aligned} \left[ \text{KC$_3$H_$_5$O$_3$}\right] & = \frac{3.005\text{ g KC$_3$H_$_5$O$_3$}}{100.\text{ mL}} \cdot \frac{1\text{ mol KC$_3$H_$_5$O$_3$}}{128.17 \text{ g KC$_3$H_$_5$O$_3$}} \cdot \frac{1000\text{ mL}}{1\text{ L}} \\ \\ &= 0.234\text{ M}\end{aligned}](https://tex.z-dn.net/?f=%5Cdisplaystyle%20%5Cbegin%7Baligned%7D%20%5Cleft%5B%20%5Ctext%7BKC%24_3%24H_%24_5%24O%24_3%24%7D%5Cright%5D%20%20%26%20%3D%20%5Cfrac%7B3.005%5Ctext%7B%20g%20KC%24_3%24H_%24_5%24O%24_3%24%7D%7D%7B100.%5Ctext%7B%20mL%7D%7D%20%5Ccdot%20%5Cfrac%7B1%5Ctext%7B%20mol%20KC%24_3%24H_%24_5%24O%24_3%24%7D%7D%7B128.17%20%5Ctext%7B%20g%20KC%24_3%24H_%24_5%24O%24_3%24%7D%7D%20%5Ccdot%20%5Cfrac%7B1000%5Ctext%7B%20mL%7D%7D%7B1%5Ctext%7B%20L%7D%7D%20%5C%5C%20%5C%5C%20%26%3D%200.234%5Ctext%7B%20M%7D%5Cend%7Baligned%7D)
By solubility rules, potassium is completely soluble, so the compound will dissociate completely into potassium and lactate ions. Therefore, [KC₃H₅O₃] = [C₃H₅O₃⁺]. Note that lactate is the conjugate base of lactic acid.
Recall the Henderson-Hasselbalch equation:
![\displaystyle \begin{aligned}\text{pH} = \text{p}K_a + \log \frac{\left[\text{Base}\right]}{\left[\text{Acid}\right]} \end{aligned}](https://tex.z-dn.net/?f=%5Cdisplaystyle%20%5Cbegin%7Baligned%7D%5Ctext%7BpH%7D%20%3D%20%5Ctext%7Bp%7DK_a%20%2B%20%5Clog%20%5Cfrac%7B%5Cleft%5B%5Ctext%7BBase%7D%5Cright%5D%7D%7B%5Cleft%5B%5Ctext%7BAcid%7D%5Cright%5D%7D%20%5Cend%7Baligned%7D)
[Base] = 0.234 M and [Acid] = 0.500 M. We are given that the resulting pH is 3.526. Substitute and solve for p<em>Kₐ</em>:
In conclusion, the p<em>Kₐ </em>value of lactic acid is about 3.856.
Explanation:
1.
i. Measure the initial volume of water in a graduated cylinder.
ii. Now submerge the irregularly shaped metal into water in a graduated cylinder.
iii. Measure the final volume of water.
iv. The difference between the final volume and the initial volume is the volume of the irregularly shaped metal.
2.
When adding the irregularly shaped metal into the glass graduated cylinder. Make sure that the irregularly shaped metal is completely submerged into the water.
Answer:
Le Châtelier's principle states that when a chemical system at equilibrium is distributed by a change in conditions, the equilibrium position will shift in a direction that tends to counteract the change.
Therefore, when there is a change in pressure, the equilibrium will counteract the change by reducing/increasing the pressure through adjusting the no. of moles of gas.
Note: At constant temperature and volume the pressure of a gas is directly proportional to the number of moles of gas.
For example, when there's an increase in total pressure, the equilibrium position will shift to the side with a smaller no. of moles of gas so as to reduce the pressure.
